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Synthesis of gamma,delta-unsaturated glycolic acids via sequenced brook and Ireland--claisen rearrangements.


ABSTRACT: Organozinc, -magnesium, and -lithium nucleophiles initiate a Brook/Ireland-Claisen rearrangement sequence of allylic silyl glyoxylates resulting in the formation of gamma,delta-unsaturated alpha-silyloxy acids.

SUBMITTER: Schmitt DC 

PROVIDER: S-EPMC2830285 | BioStudies | 2010-01-01

REPOSITORIES: biostudies

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