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Poly[bis-(?(2)-pyrimidine-?N:N')bis-(seleno-cyanato-?N)zinc].


ABSTRACT: The asymmetric unit of the title compound, [Zn(NCSe)(2)(C(4)H(4)N(2))(2)](n), consists of one Zn(2+) cation located on a special position with site symmetry 2/m, one seleno-cyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N atoms of four pyrimidine ligands and two N-bonded seleno-cyanate anions in mutually trans orientations within a slightly distorted octa-hedral coordination environment. The Zn atoms are ?-1,3-bridged via the pyrimidine ligands into a polymeric layer extending parallel to (100).

SUBMITTER: Boeckmann J 

PROVIDER: S-EPMC3151927 | BioStudies | 2011-01-01T00:00:00Z

REPOSITORIES: biostudies

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