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Studies toward the synthesis of spirolide C: exploration into the formation of the 23-membered all-carbon macrocyclic framework.


ABSTRACT: The synthesis of two complex subunits en route to spirolide C is described. A key alkyllithium addition to an aldehyde joins the fragments, which are advanced in order to investigate a ring-closing metathesis to form the 23-membered all-carbon macrocyclic framework.

SUBMITTER: Stivala CE 

PROVIDER: S-EPMC3366693 | BioStudies | 2012-01-01

REPOSITORIES: biostudies

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