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Catena-Poly[[[diaqua-(1,10-phenanthroline-?(2)N,N')cobalt(II)]-?-4-hy-droxy-3-sulfonato-benzoato-?(2)O(3):O(1)] sesquihydrate].


ABSTRACT: The 1,10-phenanthroline-chelated Co(II) atom in the polymeric title compound, {[Co(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion. It is also coordinated by two water mol-ecules in a trans-CoN(2)O(4) octa-hedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O-H?O hydrogen bonds into a three-dimensional network.

SUBMITTER: Fang XQ 

PROVIDER: S-EPMC3379066 | BioStudies | 2012-01-01T00:00:00Z

REPOSITORIES: biostudies

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