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Copper-catalyzed aerobic aliphatic C-H oxygenation with hydroperoxides.


ABSTRACT: We report herein Cu-catalyzed aerobic oxygenation of aliphatic C-H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.

SUBMITTER: Too PC 

PROVIDER: S-EPMC3701382 | BioStudies | 2013-01-01

REPOSITORIES: biostudies

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