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Palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions with aryl chlorides.


ABSTRACT: A regioselective arylation of 1,1,3-triaryl-2-azaallyl anions with aryl chlorides is described. The palladium-NIXANTPHOS-based catalyst affords diarylmethylamine derivatives in good yield and without product isomerization. A gram scale sequential one-pot ketimine synthesis/arylation protocol was also developed.

SUBMITTER: Li M 

PROVIDER: S-EPMC4136662 | BioStudies | 2014-01-01T00:00:00Z

REPOSITORIES: biostudies

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