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Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant.


ABSTRACT: An efficient Pd(II)/Pd?-p-benzoquinone/hydroquinone-CuCl?/CuCl catalyst system was developed that uses environmentally friendly molecular oxygen as the terminal oxidant to catalyze the cyclization-carbonylation-cyclization coupling reaction (CCC-coupling reaction) of (o-alkynyl phenyl) (methoxymethyl) sulfides.

SUBMITTER: Shen R 

PROVIDER: S-EPMC6273608 | BioStudies | 2016-01-01T00:00:00Z

REPOSITORIES: biostudies

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