{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Zhao Y"],"funding":["National Natural Science Foundation of China"],"pagination":["2537"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10059262"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["28(6)"],"pubmed_abstract":["Reported here is the synthesis of a macrocycle with equatorial coordination sites for the construction of self-assembled metallacages. The macrocycle is prepared <i>via</i> a post-modification on the equator of biphen[<i>n</i>]arene. Utilizing this macrocycle as a ligand, three prismatic cages and one octahedral cage were synthesized by regulating the geometric structures and coordination number of metal acceptors. The multi-cavity configuration of prismatic cage was revealed by single-crystal structure. We prove that a macrocycle with equatorial coordination sites can be an excellent building block for synthesizing structure-diverse metallacages. Our results provide a typical example and a general method for the design and synthesis of metallacages."],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["Macrocycle with Equatorial Coordination Sites Provides New Opportunity for Structure-Diverse Metallacages."],"pmcid":["PMC10059262"],"funding_grant_id":["21971192, 21772118, 21871208,22011530163"],"pubmed_authors":["Li C","Lu Y","Zhang ZY","Liu A","Zhao Y","Sue AC"],"additional_accession":[]},"is_claimable":false,"name":"Macrocycle with Equatorial Coordination Sites Provides New Opportunity for Structure-Diverse Metallacages.","description":"Reported here is the synthesis of a macrocycle with equatorial coordination sites for the construction of self-assembled metallacages. The macrocycle is prepared <i>via</i> a post-modification on the equator of biphen[<i>n</i>]arene. Utilizing this macrocycle as a ligand, three prismatic cages and one octahedral cage were synthesized by regulating the geometric structures and coordination number of metal acceptors. The multi-cavity configuration of prismatic cage was revealed by single-crystal structure. We prove that a macrocycle with equatorial coordination sites can be an excellent building block for synthesizing structure-diverse metallacages. Our results provide a typical example and a general method for the design and synthesis of metallacages.","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Mar","modification":"2025-04-22T18:16:24.024Z","creation":"2025-02-19T01:12:54.635Z"},"accession":"S-EPMC10059262","cross_references":{"pubmed":["36985508"],"doi":["10.3390/molecules28062537"]}}