{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Solea AB"],"funding":["Swiss National Science Foundation"],"pagination":["4456-4461"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10071490"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["52(14)"],"pubmed_abstract":["A molecule of luminol bound as guest inside a Co<sub>8</sub> coordination cage host undergoes oxidation by H<sub>2</sub>O<sub>2</sub> to generate chemiluminescence by a process in which the Co(II) ions in the cage superstructure activate the H<sub>2</sub>O<sub>2</sub>: accordingly the cage not only co-locates the reactants but also acts as a redox partner in the catalysis. The luminescence from oxidation of the cavity-bound luminol can transfer its excitation energy to surface-bound fluorescein molecules in an unusual example of Chemiluminescence Resonance Energy Transfer (CRET)."],"journal":["Dalton transactions (Cambridge, England : 2003)"],"pubmed_title":["A chemiluminescent lantern: a coordination cage catalysed oxidation of luminol followed by chemiluminescence resonance energy-transfer."],"pmcid":["PMC10071490"],"funding_grant_id":["Early Postdoc Mobility fellowship P2FRP2/199583"],"pubmed_authors":["Ward MD","Solea AB"],"additional_accession":[]},"is_claimable":false,"name":"A chemiluminescent lantern: a coordination cage catalysed oxidation of luminol followed by chemiluminescence resonance energy-transfer.","description":"A molecule of luminol bound as guest inside a Co<sub>8</sub> coordination cage host undergoes oxidation by H<sub>2</sub>O<sub>2</sub> to generate chemiluminescence by a process in which the Co(II) ions in the cage superstructure activate the H<sub>2</sub>O<sub>2</sub>: accordingly the cage not only co-locates the reactants but also acts as a redox partner in the catalysis. The luminescence from oxidation of the cavity-bound luminol can transfer its excitation energy to surface-bound fluorescein molecules in an unusual example of Chemiluminescence Resonance Energy Transfer (CRET).","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Apr","modification":"2025-05-29T22:23:02.537Z","creation":"2025-05-29T22:23:02.537Z"},"accession":"S-EPMC10071490","cross_references":{"pubmed":["36917490"],"doi":["10.1039/d3dt00689a"]}}