{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Wiesner T"],"funding":["China Scholarship Council","Deutsche Forschungsgemeinschaft","National Natural Science Foundation of China","Julius-Maximilians-Universität Würzburg"],"pagination":["e202201919"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10092590"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["28(69)"],"pubmed_abstract":["Tetraiodotetraazapentacene I<sub>4</sub> TAP, the last missing derivative in the series of halogenated silylated tetraazapentacenes, was synthesized via condensation chemistry from a TIPS-ethynylated diaminobenzothiadiazol in three steps. Single and double reduction furnished its air-stable monoanion and relatively air-stable dianion, both of which were characterized by crystallography. All three species are structurally and spectroscopically compared to non-halogenated TAP and Br<sub>4</sub> TAP. I<sub>4</sub> TAP is an n-channel material in thin-film transistors with average electron mobilities exceeding 1 cm<sup>2</sup> (Vs)<sup>-1</sup> ."],"journal":["Chemistry (Weinheim an der Bergstrasse, Germany)"],"pubmed_title":["The Radical Anion, Dianion and Electron Transport Properties of Tetraiodotetraazapentacene."],"pmcid":["PMC10092590"],"funding_grant_id":["22101130","PhD scholarship"],"pubmed_authors":["Wiesner T","Moos M","Ji L","Reiss H","Lambert C","Friedrich A","Freudenberg J","Dreuw A","Marder TB","Rudin B","Bunz UHF","Wu Z","Braunschweig H","Rominger F","Tverskoy O","Krummenacher I","Han J"],"additional_accession":[]},"is_claimable":false,"name":"The Radical Anion, Dianion and Electron Transport Properties of Tetraiodotetraazapentacene.","description":"Tetraiodotetraazapentacene I<sub>4</sub> TAP, the last missing derivative in the series of halogenated silylated tetraazapentacenes, was synthesized via condensation chemistry from a TIPS-ethynylated diaminobenzothiadiazol in three steps. Single and double reduction furnished its air-stable monoanion and relatively air-stable dianion, both of which were characterized by crystallography. All three species are structurally and spectroscopically compared to non-halogenated TAP and Br<sub>4</sub> TAP. I<sub>4</sub> TAP is an n-channel material in thin-film transistors with average electron mobilities exceeding 1 cm<sup>2</sup> (Vs)<sup>-1</sup> .","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Dec","modification":"2026-05-28T11:49:25.149Z","creation":"2025-04-07T03:21:56.827Z"},"accession":"S-EPMC10092590","cross_references":{"pubmed":["35916326"],"doi":["10.1002/chem.202201919"]}}