{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Linde E"],"funding":["Vetenskapsrådet"],"pagination":["e202202453"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10092902"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["28(69)"],"pubmed_abstract":["Two regioselective, high-yielding one-pot routes to oxygen-bridged cyclic diaryliodonium salts and ortho-aryloxy-substituted acyclic diaryliodonium salts are presented. Starting from easily available ortho-iodo diaryl ethers, complete selectivity in formation of either the cyclic or acyclic product could be achieved by varying the reaction conditions. The complimentary reactivities of these novel ortho-oxygenated iodonium salts were demonstrated through a series of chemoselective arylations under metal-catalyzed and metal-free conditions, to deliver a range of novel, ortho-functionalized diaryl ether derivatives."],"journal":["Chemistry (Weinheim an der Bergstrasse, Germany)"],"pubmed_title":["Synthesis of Cyclic and Acyclic ortho-Aryloxy Diaryliodonium Salts for Chemoselective Functionalizations."],"pmcid":["PMC10092902"],"funding_grant_id":["2019-04232"],"pubmed_authors":["Linde E","Olofsson B","Knippenberg N"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis of Cyclic and Acyclic ortho-Aryloxy Diaryliodonium Salts for Chemoselective Functionalizations.","description":"Two regioselective, high-yielding one-pot routes to oxygen-bridged cyclic diaryliodonium salts and ortho-aryloxy-substituted acyclic diaryliodonium salts are presented. Starting from easily available ortho-iodo diaryl ethers, complete selectivity in formation of either the cyclic or acyclic product could be achieved by varying the reaction conditions. The complimentary reactivities of these novel ortho-oxygenated iodonium salts were demonstrated through a series of chemoselective arylations under metal-catalyzed and metal-free conditions, to deliver a range of novel, ortho-functionalized diaryl ether derivatives.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Dec","modification":"2025-04-05T11:29:59.595Z","creation":"2025-04-05T11:29:59.595Z"},"accession":"S-EPMC10092902","cross_references":{"pubmed":["36083826"],"doi":["10.1002/chem.202202453"]}}