{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Tiburcio E"],"funding":["Ministero dell?Istruzione, dell?Universit? e della Ricerca","China Scholarship Council","European Research Council","Ministerio de Ciencia e Innovaci?n","European Commission","?la Caixa? Foundation","Generalitat Valenciana","Ministerio de Econom?a y Competitividad"],"pagination":["10342-10354"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10176469"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["145(18)"],"pubmed_abstract":["The combination of well-defined Fe<sup>3+</sup> isolated single-metal atoms and Ag<sub>2</sub> subnanometer metal clusters within the channels of a metal-organic framework (MOF) is reported and characterized by single-crystal X-ray diffraction for the first time. The resulting hybrid material, with the formula [Ag<sup>0</sup><sub>2</sub>(Ag<sup>0</sup>)<sub>1.34</sub>Fe<sup>III</sup><sub>0.66</sub>]@Na<sup>I</sup><sub>2</sub>{Ni<sup>II</sup><sub>4</sub>[Cu<sup>II</sup><sub>2</sub>(Me<sub>3</sub>mpba)<sub>2</sub>]<sub>3</sub>}·63H<sub>2</sub>O (<b>Fe</b><sup><b>3+</b></sup><b>Ag</b><sup><b>0</b></sup><sub><b>2</b></sub><b>@MOF</b>), is capable of catalyzing the unprecedented direct conversion of styrene to phenylacetylene in one pot. In particular, <b>Fe</b><sup><b>3+</b></sup><b>Ag</b><sup"],"journal":["Journal of the American Chemical Society"],"pubmed_title":["MOF-Triggered Synthesis of Subnanometer Ag<sup>0</sup><sub>2</sub> Clusters and Fe<sup>3+</sup> Single Atoms: Heterogenization Led to Efficient and Synergetic One-Pot Catalytic Reactions."],"pmcid":["PMC10176469"],"funding_grant_id":["PROMETEU/2021/054","PID2019104778GBI00","RYC2019- 027940-I","FJC2018035455I","CEX2019000919M","GV/2021/138","FJC2019040523I","SEJI/2020/034","202009350009","MFA/2022/048","PRTR-C17.I1","IJC2018036514I","PE0000021","PID2020115100GBI00","814804","ID100010434","LCF/BQ/PR19/11700011"],"pubmed_authors":["Hernandez-Garrido JC","Zheng Y","Leyva-Perez A","Oliver-Meseguer J","Vidal-Moya A","Tiburcio E","Mon M","Martin N","Bilanin C","Ferrando-Soria J","Armentano D","Pardo E"],"additional_accession":[]},"is_claimable":false,"name":"MOF-Triggered Synthesis of Subnanometer Ag<sup>0</sup><sub>2</sub> Clusters and Fe<sup>3+</sup> Single Atoms: Heterogenization Led to Efficient and Synergetic One-Pot Catalytic Reactions.","description":"The combination of well-defined Fe<sup>3+</sup> isolated single-metal atoms and Ag<sub>2</sub> subnanometer metal clusters within the channels of a metal-organic framework (MOF) is reported and characterized by single-crystal X-ray diffraction for the first time. The resulting hybrid material, with the formula [Ag<sup>0</sup><sub>2</sub>(Ag<sup>0</sup>)<sub>1.34</sub>Fe<sup>III</sup><sub>0.66</sub>]@Na<sup>I</sup><sub>2</sub>{Ni<sup>II</sup><sub>4</sub>[Cu<sup>II</sup><sub>2</sub>(Me<sub>3</sub>mpba)<sub>2</sub>]<sub>3</sub>}·63H<sub>2</sub>O (<b>Fe</b><sup><b>3+</b></sup><b>Ag</b><sup><b>0</b></sup><sub><b>2</b></sub><b>@MOF</b>), is capable of catalyzing the unprecedented direct conversion of styrene to phenylacetylene in one pot. In particular, <b>Fe</b><sup><b>3+</b></sup><b>Ag</b><sup","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 May","modification":"2025-04-26T14:33:15.483Z","creation":"2025-04-06T14:34:26.51Z"},"accession":"S-EPMC10176469","cross_references":{"pubmed":["37115008"],"doi":["10.1021/jacs.3c02155"]}}