biostudies-literatureTiburcio EMinistero dell?Istruzione, dell?Universit? e della RicercaChina Scholarship CouncilEuropean Research CouncilMinisterio de Ciencia e Innovaci?nEuropean Commission?la Caixa? FoundationGeneralitat ValencianaMinisterio de Econom?a y Competitividad10342-10354https://www.ebi.ac.uk/biostudies/studies/S-EPMC10176469biostudies-literatureUnknown145(18)The combination of well-defined Fe³⁺ isolated single-metal atoms and Ag₂ subnanometer metal clusters within the channels of a metal-organic framework (MOF) is reported and characterized by single-crystal X-ray diffraction for the first time. The resulting hybrid material, with the formula [Ag⁰₂(Ag⁰)_1.34Fe^III_0.66]@Na^I₂{Ni^II₄[Cu^II₂(Me₃mpba)₂]₃}·63H₂O (<b>Fe</b>^<b>3+</b><b>Ag</b>^<b>0</b>_<b>2</b><b>@MOF</b>), is capable of catalyzing the unprecedented direct conversion of styrene to phenylacetylene in one pot. In particular, <b>Fe</b>^<b>3+</b><b>Ag</b><supJournal of the American Chemical SocietyMOF-Triggered Synthesis of Subnanometer Ag⁰₂ Clusters and Fe³⁺ Single Atoms: Heterogenization Led to Efficient and Synergetic One-Pot Catalytic Reactions.PMC10176469PROMETEU/2021/054PID2019104778GBI00RYC2019- 027940-IFJC2018035455ICEX2019000919MGV/2021/138FJC2019040523ISEJI/2020/034202009350009MFA/2022/048PRTR-C17.I1IJC2018036514IPE0000021PID2020115100GBI00814804ID100010434LCF/BQ/PR19/11700011Hernandez-Garrido JCZheng YLeyva-Perez AOliver-Meseguer JVidal-Moya ATiburcio EMon MMartin NBilanin CFerrando-Soria JArmentano DPardo EfalseMOF-Triggered Synthesis of Subnanometer Ag⁰₂ Clusters and Fe³⁺ Single Atoms: Heterogenization Led to Efficient and Synergetic One-Pot Catalytic Reactions.The combination of well-defined Fe³⁺ isolated single-metal atoms and Ag₂ subnanometer metal clusters within the channels of a metal-organic framework (MOF) is reported and characterized by single-crystal X-ray diffraction for the first time. The resulting hybrid material, with the formula [Ag⁰₂(Ag⁰)_1.34Fe^III_0.66]@Na^I₂{Ni^II₄[Cu^II₂(Me₃mpba)₂]₃}·63H₂O (<b>Fe</b>^<b>3+</b><b>Ag</b>^<b>0</b>_<b>2</b><b>@MOF</b>), is capable of catalyzing the unprecedented direct conversion of styrene to phenylacetylene in one pot. In particular, <b>Fe</b>^<b>3+</b><b>Ag</b><sup2023-01-01T00:00:00Z2023 May2025-04-26T14:33:15.483Z2025-04-06T14:34:26.51ZS-EPMC101764693711500810.1021/jacs.3c02155