{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["14(19)"],"submitter":["Cheng X"],"pubmed_abstract":["In nature, the communication of primary amino acids in the polypeptides influences molecular-level packing, supramolecular chirality, and the resulting protein structures. In chiral side-chain liquid crystalline polymers (SCLCPs), however, the hierarchical chiral communication between supramolecular mesogens is still determined by the parent chiral source due to the intermolecular interactions. Herein, we present a novel strategy to enable the tunable chiral-to-chiral communication in azobenzene (Azo) SCLCPs, in which the chiroptical properties are not dominated by the configurational point chirality but by the conformationally supramolecular chirality that emerged. The communication of dyads biases supramolecular chirality with multiple packing preference, thereby overruling the configura"],"journal":["Chemical science"],"pagination":["5116-5124"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10189893"],"repository":["biostudies-literature"],"pubmed_title":["Conformationally supramolecular chirality prevails over configurational point chirality in side-chain liquid crystalline polymers."],"pmcid":["PMC10189893"],"pubmed_authors":["Zhang G","Zhang W","Zhang Z","Song Q","Gan Y","Cheng X"],"additional_accession":[]},"is_claimable":false,"name":"Conformationally supramolecular chirality prevails over configurational point chirality in side-chain liquid crystalline polymers.","description":"In nature, the communication of primary amino acids in the polypeptides influences molecular-level packing, supramolecular chirality, and the resulting protein structures. In chiral side-chain liquid crystalline polymers (SCLCPs), however, the hierarchical chiral communication between supramolecular mesogens is still determined by the parent chiral source due to the intermolecular interactions. Herein, we present a novel strategy to enable the tunable chiral-to-chiral communication in azobenzene (Azo) SCLCPs, in which the chiroptical properties are not dominated by the configurational point chirality but by the conformationally supramolecular chirality that emerged. The communication of dyads biases supramolecular chirality with multiple packing preference, thereby overruling the configura","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 May","modification":"2025-04-19T06:41:20.559Z","creation":"2025-04-19T06:41:20.559Z"},"accession":"S-EPMC10189893","cross_references":{"pubmed":["37206386"],"doi":["10.1039/d3sc00975k"]}}