{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ullah S"],"funding":["King Saud University"],"pagination":["693"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10224544"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["16(5)"],"pubmed_abstract":["Six heteroleptic Cu(II) carboxylates (<b>1</b>-<b>6</b>) were prepared by reacting 2-chlorophenyl acetic acid (<b>L<sup>1</sup></b>), 3-chlorophenyl acetic acid (<b>L<sup>2</sup></b>), and substituted pyridine (2-cyanopyridine and 2-chlorocyanopyridine). The solid-state behavior of the complexes was described via vibrational spectroscopy (FT-IR), which revealed that the carboxylate moieties adopted different coordination modes around the Cu(II) center. A paddlewheel dinuclear structure with distorted square pyramidal geometry was elucidated from the crystal data for complexes <b>2</b> and <b>5</b> with substituted pyridine moieties at the axial positions. The presence of irreversible metal-centered oxidation reduction peaks confirms the electroactive nature of the complexes. A relatively h"],"journal":["Pharmaceuticals (Basel, Switzerland)"],"pubmed_title":["Synthesis, Structural Elucidation and Pharmacological Applications of Cu(II) Heteroleptic Carboxylates."],"pmcid":["PMC10224544"],"funding_grant_id":["RSP2023R357"],"pubmed_authors":["Rehman MU","Ullah S","Naz S","Zubair M","Sirajuddin M","Ali S","Kubicki M","Zargar S","Ullah Z","Wani TA","Mushtaq A","Haider A"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis, Structural Elucidation and Pharmacological Applications of Cu(II) Heteroleptic Carboxylates.","description":"Six heteroleptic Cu(II) carboxylates (<b>1</b>-<b>6</b>) were prepared by reacting 2-chlorophenyl acetic acid (<b>L<sup>1</sup></b>), 3-chlorophenyl acetic acid (<b>L<sup>2</sup></b>), and substituted pyridine (2-cyanopyridine and 2-chlorocyanopyridine). The solid-state behavior of the complexes was described via vibrational spectroscopy (FT-IR), which revealed that the carboxylate moieties adopted different coordination modes around the Cu(II) center. A paddlewheel dinuclear structure with distorted square pyramidal geometry was elucidated from the crystal data for complexes <b>2</b> and <b>5</b> with substituted pyridine moieties at the axial positions. The presence of irreversible metal-centered oxidation reduction peaks confirms the electroactive nature of the complexes. A relatively h","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 May","modification":"2025-05-29T16:22:12.851Z","creation":"2025-05-29T16:22:12.851Z"},"accession":"S-EPMC10224544","cross_references":{"pubmed":["37242476"],"doi":["10.3390/ph16050693"]}}