{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["14(22)"],"submitter":["Kundu G"],"pubmed_abstract":["Despite recent advancements in the chemistry of multiply bound boron compounds, the laboratory isolation of the parent oxoborane moiety, HBO has long remained an unsolved and well-recognized challenge. The reaction of 6-SIDipp·BH<sub>3</sub> [6-SIDipp = 1,3-di(2,6-diisopropylphenyl)tetrahydropyrimidine-2-ylidene] with GaCl<sub>3</sub> afforded an unusual boron-gallium 3c-2e compound (1). The addition of water to 1 resulted in the release of H<sub>2</sub> and the formation of a rare acid stabilized neutral parent oxoborane, LB(H)[double bond, length as m-dash]O (2). Crystallographic and density functional theory (DFT) analyses support the presence of a terminal B[double bond, length as m-dash]O double bond. Subsequent addition of another equivalent of water molecule led to hydrolysis of the"],"journal":["Chemical science"],"pagination":["5894-5898"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10246693"],"repository":["biostudies-literature"],"pubmed_title":["Taming the parent oxoborane."],"pmcid":["PMC10246693"],"pubmed_authors":["Sen SS","Amrutha PR","Raj KV","Vanka K","Kundu G","Tothadi S"],"additional_accession":[]},"is_claimable":false,"name":"Taming the parent oxoborane.","description":"Despite recent advancements in the chemistry of multiply bound boron compounds, the laboratory isolation of the parent oxoborane moiety, HBO has long remained an unsolved and well-recognized challenge. The reaction of 6-SIDipp·BH<sub>3</sub> [6-SIDipp = 1,3-di(2,6-diisopropylphenyl)tetrahydropyrimidine-2-ylidene] with GaCl<sub>3</sub> afforded an unusual boron-gallium 3c-2e compound (1). The addition of water to 1 resulted in the release of H<sub>2</sub> and the formation of a rare acid stabilized neutral parent oxoborane, LB(H)[double bond, length as m-dash]O (2). Crystallographic and density functional theory (DFT) analyses support the presence of a terminal B[double bond, length as m-dash]O double bond. Subsequent addition of another equivalent of water molecule led to hydrolysis of the","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Jun","modification":"2025-04-27T02:22:42.14Z","creation":"2025-04-06T18:31:06.867Z"},"accession":"S-EPMC10246693","cross_references":{"pubmed":["37293651"],"doi":["10.1039/d3sc01544k"]}}