{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Grilli D"],"funding":["Danmarks Frie Forskningsfond","Energimyndigheten","Erasmus+"],"pagination":["10736-10742"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10336971"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["62(27)"],"pubmed_abstract":["A series of four homologous silicides have been discovered during systematic explorations in the central part of the La-Ni-Si system at 1000 °C. All compounds La<sub>12.5</sub>Ni<sub>28.0</sub>Si<sub>18.3</sub> (<i>n</i> = 3; <i>a</i> = 28.8686(8), <i>c</i> = 4.0737(2) Å, <i>Z</i> = 3), La<sub>22.1</sub>Ni<sub>39.0</sub>Si<sub>27.8</sub> (<i>n</i> = 4; <i>a</i> = 20.9340(6), <i>c</i> = 4.1245(2) Å, <i>Z</i> = 1), La<sub>32.9</sub>Ni<sub>49.8</sub>Si<sub>39.3</sub> (<i>n</i> = 5; <i>a</i> = 24.946(1), <i>c</i> = 4.1471(5) Å, <i>Z</i> = 1), and La<sub>44.8</sub>Ni<sub>66.1</sub>Si<sub>53.4</sub> (<i>n</i> = 6; <i>a</i> = 28.995(5), <i>c</i> = 4.158(1) Å, <i>Z</i> = 1) crystallize in the hexagonal space group <i>P</i>6<sub>3</sub>/<i>m</i> and can be generalized according to La<sub><i>n</i>(<"],"journal":["Inorganic chemistry"],"pubmed_title":["La<sub><i>n</i>(<i>n</i>+1)+<i>x</i></sub>Ni<sub><i>n</i>(<i>n</i>+5)+<i>y</i></sub>Si<sub>(<i>n</i>+1)(<i>n</i>+2)-<i>z</i></sub>: A Symmetric Mirror Homologous Series in the La-Ni-Si System."],"pmcid":["PMC10336971"],"funding_grant_id":["48699-1","10.46540/2102-00143B"],"pubmed_authors":["Smetana V","Ahmed SJ","Grilli D","Pani M","Manfrinetti P","Mudring AV","Shtender V"],"additional_accession":[]},"is_claimable":false,"name":"La<sub><i>n</i>(<i>n</i>+1)+<i>x</i></sub>Ni<sub><i>n</i>(<i>n</i>+5)+<i>y</i></sub>Si<sub>(<i>n</i>+1)(<i>n</i>+2)-<i>z</i></sub>: A Symmetric Mirror Homologous Series in the La-Ni-Si System.","description":"A series of four homologous silicides have been discovered during systematic explorations in the central part of the La-Ni-Si system at 1000 °C. All compounds La<sub>12.5</sub>Ni<sub>28.0</sub>Si<sub>18.3</sub> (<i>n</i> = 3; <i>a</i> = 28.8686(8), <i>c</i> = 4.0737(2) Å, <i>Z</i> = 3), La<sub>22.1</sub>Ni<sub>39.0</sub>Si<sub>27.8</sub> (<i>n</i> = 4; <i>a</i> = 20.9340(6), <i>c</i> = 4.1245(2) Å, <i>Z</i> = 1), La<sub>32.9</sub>Ni<sub>49.8</sub>Si<sub>39.3</sub> (<i>n</i> = 5; <i>a</i> = 24.946(1), <i>c</i> = 4.1471(5) Å, <i>Z</i> = 1), and La<sub>44.8</sub>Ni<sub>66.1</sub>Si<sub>53.4</sub> (<i>n</i> = 6; <i>a</i> = 28.995(5), <i>c</i> = 4.158(1) Å, <i>Z</i> = 1) crystallize in the hexagonal space group <i>P</i>6<sub>3</sub>/<i>m</i> and can be generalized according to La<sub><i>n</i>(<","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Jul","modification":"2025-04-04T13:52:34.312Z","creation":"2025-04-04T13:52:34.312Z"},"accession":"S-EPMC10336971","cross_references":{"pubmed":["37364160"],"doi":["10.1021/acs.inorgchem.3c01194"]}}