{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["13(34)"],"submitter":["Lee CJ"],"pubmed_abstract":["A robust porous organic polymer cross-linked by Sn(iv) porphyrin (SnPOP) was fabricated by reacting <i>trans</i>-dihydroxo-[5,15,10,20-tetrakis(phenyl)porphyrinato]tin(iv) (SnP) with fluorinated polyimide (FPI) <i>via</i> sol-gel formation, followed by supercritical CO<sub>2</sub> drying. The structural and porous properties of SnPOP were characterized using FT-IR, UV-vis, and fluorescence spectroscopies, along with field-emission scanning electron microscopy and gas sorption experiments. The reaction between the SnP's oxophilic Sn(iv) center and FPI's carboxylic acid moiety resulted in a controllable cross-linked porous texture. This material features the desirable physical properties of porphyrin and exhibits mesoporous structures with a relatively high surface area. SnPOP is thermally s"],"journal":["RSC advances"],"pagination":["24077-24085"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10415751"],"repository":["biostudies-literature"],"pubmed_title":["Fabrication and properties of Sn(iv) porphyrin-linked porous organic polymer for environmental applications."],"pmcid":["PMC10415751"],"pubmed_authors":["Shee NK","Lee CJ","Kim HJ"],"additional_accession":[]},"is_claimable":false,"name":"Fabrication and properties of Sn(iv) porphyrin-linked porous organic polymer for environmental applications.","description":"A robust porous organic polymer cross-linked by Sn(iv) porphyrin (SnPOP) was fabricated by reacting <i>trans</i>-dihydroxo-[5,15,10,20-tetrakis(phenyl)porphyrinato]tin(iv) (SnP) with fluorinated polyimide (FPI) <i>via</i> sol-gel formation, followed by supercritical CO<sub>2</sub> drying. The structural and porous properties of SnPOP were characterized using FT-IR, UV-vis, and fluorescence spectroscopies, along with field-emission scanning electron microscopy and gas sorption experiments. The reaction between the SnP's oxophilic Sn(iv) center and FPI's carboxylic acid moiety resulted in a controllable cross-linked porous texture. This material features the desirable physical properties of porphyrin and exhibits mesoporous structures with a relatively high surface area. SnPOP is thermally s","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Aug","modification":"2025-04-04T10:09:34.669Z","creation":"2025-04-04T10:09:34.669Z"},"accession":"S-EPMC10415751","cross_references":{"pubmed":["37577097"],"doi":["10.1039/d3ra04117d"]}}