{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Choi SJ"],"funding":["Rural Development Administration"],"pagination":["29770-29778"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10433477"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["8(32)"],"pubmed_abstract":["Ethylene is a gaseous hydrocarbon molecule known as a plant hormone that promotes fruit ripening and senescence. Efficiently controlling ethylene is a central key to maintaining the quality of agricultural products. The current study uncovered a synthetic method for 1-(2,2-dimethylpropyl)-cyclopropene (1-DCP) as a cyclopropene derivative to inhibit ethylene action in fruit ripening and senescence. We synthesized 1-DCP using α-diisobutylene through a two-step process, including allylic chlorination by hypochlorite and HCl, followed by α-elimination of the allylic chloride using a strong base, lithium diethylamide. GC-MS and NMR analyses demonstrated that 1-DCP was synthesized efficiently with 35% yield and 95% purity. When treated as an aqueous emulsion on plants, including persimmon and ba"],"journal":["ACS omega"],"pubmed_title":["Synthesis of 1-(2,2-Dimethylpropyl)-Cyclopropene (1-DCP) as an Ethylene Antagonist."],"pmcid":["PMC10433477"],"funding_grant_id":["PJ01696801"],"pubmed_authors":["Jahng WJ","Choi SJ","Ahn GH","Lee KH"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis of 1-(2,2-Dimethylpropyl)-Cyclopropene (1-DCP) as an Ethylene Antagonist.","description":"Ethylene is a gaseous hydrocarbon molecule known as a plant hormone that promotes fruit ripening and senescence. Efficiently controlling ethylene is a central key to maintaining the quality of agricultural products. The current study uncovered a synthetic method for 1-(2,2-dimethylpropyl)-cyclopropene (1-DCP) as a cyclopropene derivative to inhibit ethylene action in fruit ripening and senescence. We synthesized 1-DCP using α-diisobutylene through a two-step process, including allylic chlorination by hypochlorite and HCl, followed by α-elimination of the allylic chloride using a strong base, lithium diethylamide. GC-MS and NMR analyses demonstrated that 1-DCP was synthesized efficiently with 35% yield and 95% purity. When treated as an aqueous emulsion on plants, including persimmon and ba","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Aug","modification":"2026-05-29T08:03:13.408Z","creation":"2024-11-07T09:54:39.398Z"},"accession":"S-EPMC10433477","cross_references":{"pubmed":["37599926"],"doi":["10.1021/acsomega.3c04220"]}}