{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Min Y"],"funding":["National Natural Science Foundation of China","National Natural Science Foundation of China (National Science Foundation of China)"],"pagination":["5134"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10447495"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["14(1)"],"pubmed_abstract":["Electrochemical technology is a robust approach to removing toxic and persistent chlorinated organic pollutants from water; however, it remains a challenge to design electrocatalysts with high activity and selectivity as elaborately as natural reductive dehalogenases. Here we report the design of high-performance electrocatalysts toward water dechlorination by mimicking the binding pocket configuration and catalytic center of reductive dehalogenases. Specifically, our designed electrocatalyst is an assembled heterostructure by sandwiching a molecular catalyst into the interlayers of two-dimensional graphene oxide. The electrocatalyst exhibits excellent dechlorination performance, which enhances reduction of intermediate dichloroacetic acid by 7.8 folds against that without sandwich configu"],"journal":["Nature communications"],"pubmed_title":["Mimicking reductive dehalogenases for efficient electrocatalytic water dechlorination."],"pmcid":["PMC10447495"],"funding_grant_id":["22232003"],"pubmed_authors":["Xiong Y","Pan XQ","Min Y","Yu HQ","Chen JJ","Mei SC"],"additional_accession":[]},"is_claimable":false,"name":"Mimicking reductive dehalogenases for efficient electrocatalytic water dechlorination.","description":"Electrochemical technology is a robust approach to removing toxic and persistent chlorinated organic pollutants from water; however, it remains a challenge to design electrocatalysts with high activity and selectivity as elaborately as natural reductive dehalogenases. Here we report the design of high-performance electrocatalysts toward water dechlorination by mimicking the binding pocket configuration and catalytic center of reductive dehalogenases. Specifically, our designed electrocatalyst is an assembled heterostructure by sandwiching a molecular catalyst into the interlayers of two-dimensional graphene oxide. The electrocatalyst exhibits excellent dechlorination performance, which enhances reduction of intermediate dichloroacetic acid by 7.8 folds against that without sandwich configu","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Aug","modification":"2026-04-29T02:32:34.567Z","creation":"2025-02-19T04:02:12.311Z"},"accession":"S-EPMC10447495","cross_references":{"pubmed":["37612275"],"doi":["10.1038/s41467-023-40906-6"]}}