{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Fitch SDS"],"funding":["Engineering and Physical Sciences Research Council"],"pagination":["39198-39210"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10450643"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["15(33)"],"pubmed_abstract":["Li<sub>3</sub>N is an excellent protective coating material for lithium electrodes with very high lithium-ion conductivity and low electronic conductivity, but the formation of stable and homogeneous coatings is technically very difficult. Here, we show that protective Li<sub>3</sub>N coatings can be simply formed by the direct reaction of electrodeposited lithium electrodes with N<sub>2</sub> gas, whereas using battery-grade lithium foil is problematic due to the presence of a native passivation layer that hampers that reaction. The protective Li<sub>3</sub>N coating is effective at preventing lithium dendrite formation, as found from unidirectional plating and plating-stripping measurements in Li-Li cells. The Li<sub>3</sub>N coating also efficiently suppresses the parasitic reactions of"],"journal":["ACS applied materials & interfaces"],"pubmed_title":["Combined Electrochemical, XPS, and STXM Study of Lithium Nitride as a Protective Coating for Lithium Metal and Lithium-Sulfur Batteries."],"pmcid":["PMC10450643"],"funding_grant_id":["EP/N024303/1","EP/S003053/1","FIRG014"],"pubmed_authors":["Meddings N","Lee TL","Garcia-Araez N","Fop S","Fitch SDS","Moehl GE","Soule S","Kazemian M","Hector AL"],"additional_accession":[]},"is_claimable":false,"name":"Combined Electrochemical, XPS, and STXM Study of Lithium Nitride as a Protective Coating for Lithium Metal and Lithium-Sulfur Batteries.","description":"Li<sub>3</sub>N is an excellent protective coating material for lithium electrodes with very high lithium-ion conductivity and low electronic conductivity, but the formation of stable and homogeneous coatings is technically very difficult. Here, we show that protective Li<sub>3</sub>N coatings can be simply formed by the direct reaction of electrodeposited lithium electrodes with N<sub>2</sub> gas, whereas using battery-grade lithium foil is problematic due to the presence of a native passivation layer that hampers that reaction. The protective Li<sub>3</sub>N coating is effective at preventing lithium dendrite formation, as found from unidirectional plating and plating-stripping measurements in Li-Li cells. The Li<sub>3</sub>N coating also efficiently suppresses the parasitic reactions of","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Aug","modification":"2025-04-04T07:13:27.262Z","creation":"2024-11-20T23:49:53.322Z"},"accession":"S-EPMC10450643","cross_references":{"pubmed":["37552207"],"doi":["10.1021/acsami.3c04897"]}}