{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Diaz J"],"funding":["National Agency For Research and Development - Chile"],"pagination":["6368"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10490183"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["28(17)"],"pubmed_abstract":["The catalytic oxidation of phenethoxybenzene as a lignin model compound with a β-O-4 bond was conducted using the Keggin-type polyoxometalate nanocatalyst (TBA)<sub>5</sub>[PMo<sub>10</sub>V<sub>2</sub>O<sub>40</sub>]. The optimization of the process's operational conditions was carried out using response surface methodology. The statistically significant variables in the process were determined using a fractional factorial design. Based on this selection, a central circumscribed composite experimental design was used to maximize the phenethoxybenzene conversion, varying temperature, reaction time, and catalyst load. The optimal conditions that maximized the phenethoxybenzene conversion were 137 °C, 3.5 h, and 200 mg of catalyst. In addition, under the optimized conditions, the Kraft ligni"],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["Catalytic Selective Oxidation of β-O-4 Bond in Phenethoxybenzene as a Lignin Model Using (TBA)<sub>5</sub>[PMo<sub>10</sub>V<sub>2</sub>O<sub>40</sub>] Nanocatalyst: Optimization of Operational Conditions."],"pmcid":["PMC10490183"],"funding_grant_id":["1201895"],"pubmed_authors":["Campos CH","Melin V","Azocar L","Contreras D","Diaz J","Pizzio LR","Briones R","Pecchi G","Murillo-Sierra JC","Romero R","Troncoso E","Mendez-Rivas C"],"additional_accession":[]},"is_claimable":false,"name":"Catalytic Selective Oxidation of β-O-4 Bond in Phenethoxybenzene as a Lignin Model Using (TBA)<sub>5</sub>[PMo<sub>10</sub>V<sub>2</sub>O<sub>40</sub>] Nanocatalyst: Optimization of Operational Conditions.","description":"The catalytic oxidation of phenethoxybenzene as a lignin model compound with a β-O-4 bond was conducted using the Keggin-type polyoxometalate nanocatalyst (TBA)<sub>5</sub>[PMo<sub>10</sub>V<sub>2</sub>O<sub>40</sub>]. The optimization of the process's operational conditions was carried out using response surface methodology. The statistically significant variables in the process were determined using a fractional factorial design. Based on this selection, a central circumscribed composite experimental design was used to maximize the phenethoxybenzene conversion, varying temperature, reaction time, and catalyst load. The optimal conditions that maximized the phenethoxybenzene conversion were 137 °C, 3.5 h, and 200 mg of catalyst. In addition, under the optimized conditions, the Kraft ligni","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Aug","modification":"2025-04-04T03:19:15.582Z","creation":"2025-02-19T01:55:39.002Z"},"accession":"S-EPMC10490183","cross_references":{"pubmed":["37687197"],"doi":["10.3390/molecules28176368"]}}