{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["88(21)"],"submitter":["Iii RC"],"funding":["Office of Research and Economic Development, University of California, Riverside"],"pubmed_abstract":["Manipulating carbon-centered radicals to add to electron-deficient systems is a well-precedented process. By coupling the Fe(II)-mediated Fenton reaction with the Fe(III)-mediated single-electron oxidation of anisolic compounds, we demonstrate how electron-rich carbon-centered radicals can react with electron-rich arenes through a radical-polar cascade pathway. This bioinspired approach produces diarylmethane derivatives from simple unfunctionalized precursors."],"journal":["The Journal of organic chemistry"],"pagination":["15060-15066"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10629232"],"repository":["biostudies-literature"],"pubmed_title":["A Fenton Approach to Aromatic Radical Cations and Diarylmethane Synthesis."],"pmcid":["PMC10629232"],"pubmed_authors":["Iii RC","Lujan B","DeBow JD","Manasi R","Martinez A","Kou KGM"],"additional_accession":[]},"is_claimable":false,"name":"A Fenton Approach to Aromatic Radical Cations and Diarylmethane Synthesis.","description":"Manipulating carbon-centered radicals to add to electron-deficient systems is a well-precedented process. By coupling the Fe(II)-mediated Fenton reaction with the Fe(III)-mediated single-electron oxidation of anisolic compounds, we demonstrate how electron-rich carbon-centered radicals can react with electron-rich arenes through a radical-polar cascade pathway. This bioinspired approach produces diarylmethane derivatives from simple unfunctionalized precursors.","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Nov","modification":"2025-04-05T10:23:12.533Z","creation":"2025-04-05T10:23:12.533Z"},"accession":"S-EPMC10629232","cross_references":{"pubmed":["37847050"],"doi":["10.1021/acs.joc.3c01505"]}}