{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Khoo RSH"],"funding":["Basic Energy Sciences"],"pagination":["24052-24060"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10636760"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["145(44)"],"pubmed_abstract":["Heterogeneous catalysis plays an indispensable role in chemical production and energy conversion. Incorporation of transition metals into metal oxides and zeolites is a common strategy to fine-tune the activity and selectivity of the resulting solid catalysts, as either the active center or promotor. Studying the underlying mechanism is however challenging. Decorating the metal-oxo clusters with transition metals in metal-organic frameworks (MOFs) via postsynthetic modification offers a rational approach to construct well-defined structural models for better understanding of the reaction mechanism. Therefore, it is important to expand the materials scope beyond the currently widely studied zirconium MOFs consisting of Zr<sub>6</sub> nodes. In this work, we report the design and synthesis o"],"journal":["Journal of the American Chemical Society"],"pubmed_title":["Postsynthetic Modification of the Nonanuclear Node in a Zirconium Metal-Organic Framework for Photocatalytic Oxidation of Hydrocarbons."],"pmcid":["PMC10636760"],"funding_grant_id":["DE-AC02-05CH11231"],"pubmed_authors":["Liu Y","Khoo RSH","Huang J","Zhang J","Hu W","Lu J","Zhang X","Fiankor C","Morton MD","Yang S","Yang C"],"additional_accession":[]},"is_claimable":false,"name":"Postsynthetic Modification of the Nonanuclear Node in a Zirconium Metal-Organic Framework for Photocatalytic Oxidation of Hydrocarbons.","description":"Heterogeneous catalysis plays an indispensable role in chemical production and energy conversion. Incorporation of transition metals into metal oxides and zeolites is a common strategy to fine-tune the activity and selectivity of the resulting solid catalysts, as either the active center or promotor. Studying the underlying mechanism is however challenging. Decorating the metal-oxo clusters with transition metals in metal-organic frameworks (MOFs) via postsynthetic modification offers a rational approach to construct well-defined structural models for better understanding of the reaction mechanism. Therefore, it is important to expand the materials scope beyond the currently widely studied zirconium MOFs consisting of Zr<sub>6</sub> nodes. In this work, we report the design and synthesis o","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Nov","modification":"2025-04-05T00:01:46.981Z","creation":"2025-04-05T00:01:46.981Z"},"accession":"S-EPMC10636760","cross_references":{"pubmed":["37880201"],"doi":["10.1021/jacs.3c07237"]}}