{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Fernandez-Palacios S"],"funding":["Ministerio de Ciencia, Innovacion y Universidades","Ministerio de Ciencia, Innovación y Universidades","Junta de Andalucia"],"pagination":["14739"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10648745"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["24(19)"],"pubmed_abstract":["A family of acylhydrazones have been prepared and characterized with the aim of investigating their potential as information storage systems. Their well-established synthetic methodologies allowed for the preparation of seven chemically stable acylhydrazones in excellent yields that have been photophysically and photochemically characterized. In addition, DFT and TD-DFT calculations have been performed to gain more insights into the structural, energetic and photophysical properties of the <i>E</i>/<i>Z</i> isomers. Our results reveal that <i>E</i>/<i>Z</i> configurational isomerization upon irradiation is highly dependent on the stabilization of the <i>E</i> or <i>Z</i> isomers due to the formation of intramolecular H bonds and the electronic/steric effects intrinsically related to their "],"journal":["International journal of molecular sciences"],"pubmed_title":["New Insights into Acylhydrazones <i>E</i>/<i>Z</i> Isomerization: An Experimental and Theoretical Approach."],"pmcid":["PMC10648745"],"funding_grant_id":["PID2019-110305GB-I00","FQM-159","FQM-017","PID2019-104293GB-I00"],"pubmed_authors":["Lopez Navarrete JT","Matamoros E","Morato Rojas I","Perez-Inestrosa E","Ruiz Delgado MC","Fernandez-Palacios S","Vida Y"],"additional_accession":[]},"is_claimable":false,"name":"New Insights into Acylhydrazones <i>E</i>/<i>Z</i> Isomerization: An Experimental and Theoretical Approach.","description":"A family of acylhydrazones have been prepared and characterized with the aim of investigating their potential as information storage systems. Their well-established synthetic methodologies allowed for the preparation of seven chemically stable acylhydrazones in excellent yields that have been photophysically and photochemically characterized. In addition, DFT and TD-DFT calculations have been performed to gain more insights into the structural, energetic and photophysical properties of the <i>E</i>/<i>Z</i> isomers. Our results reveal that <i>E</i>/<i>Z</i> configurational isomerization upon irradiation is highly dependent on the stabilization of the <i>E</i> or <i>Z</i> isomers due to the formation of intramolecular H bonds and the electronic/steric effects intrinsically related to their ","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Sep","modification":"2025-04-26T17:14:00.73Z","creation":"2025-04-06T15:29:53.796Z"},"accession":"S-EPMC10648745","cross_references":{"pubmed":["37834186"],"doi":["10.3390/ijms241914739"]}}