{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["8(45)"],"submitter":["Calzada LA"],"pubmed_abstract":["The influence of the acid sites in the hydrodeoxygenation of anisole performed over Ni catalysts supported on SBA-15 modified with metal oxides (Ni/M-SBA-15, M = Ti, Zr, Al, or Nb) was demonstrated. Catalysts were characterized by SEM-EDX, nitrogen physisorption, XRD, UV-visible DRS, TPR, TPD of ammonia, IR-Py, O<sub>2</sub> chemisorption, and high-resolution transmission electron microscopy. The mesoporous structure and the hexagonal arrangement of the supports were maintained in the catalysts. Ni catalysts supported on modified M-SBA-15 exhibited a higher metal-support interaction, an increase in the acidity and, as a consequence, improved selectivity to cyclohexane. The deoxygenation reaction rate constants increased as Ni/SBA-15 < Ni/Ti-SBA-15 < Ni/Nb-SBA-15 < Ni/Zr-SBA-15 < Ni/Al-SBA-"],"journal":["ACS omega"],"pagination":["42849-42866"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10652737"],"repository":["biostudies-literature"],"pubmed_title":["Boosting the Hydrodeoxygenation Activity and Selectivity of Ni/(M)-SBA-15 Catalysts by Chemical Alteration of the Support."],"pmcid":["PMC10652737"],"pubmed_authors":["Calzada LA","Sanchez-Ramirez M","Gomez-Cortes A","Klimova TE","Perez-Estrada D","Diaz G","Gomora-Herrera D"],"additional_accession":[]},"is_claimable":false,"name":"Boosting the Hydrodeoxygenation Activity and Selectivity of Ni/(M)-SBA-15 Catalysts by Chemical Alteration of the Support.","description":"The influence of the acid sites in the hydrodeoxygenation of anisole performed over Ni catalysts supported on SBA-15 modified with metal oxides (Ni/M-SBA-15, M = Ti, Zr, Al, or Nb) was demonstrated. Catalysts were characterized by SEM-EDX, nitrogen physisorption, XRD, UV-visible DRS, TPR, TPD of ammonia, IR-Py, O<sub>2</sub> chemisorption, and high-resolution transmission electron microscopy. The mesoporous structure and the hexagonal arrangement of the supports were maintained in the catalysts. Ni catalysts supported on modified M-SBA-15 exhibited a higher metal-support interaction, an increase in the acidity and, as a consequence, improved selectivity to cyclohexane. The deoxygenation reaction rate constants increased as Ni/SBA-15 < Ni/Ti-SBA-15 < Ni/Nb-SBA-15 < Ni/Zr-SBA-15 < Ni/Al-SBA-","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Nov","modification":"2025-04-05T00:24:31.886Z","creation":"2025-04-05T00:24:31.886Z"},"accession":"S-EPMC10652737","cross_references":{"pubmed":["38024772"],"doi":["10.1021/acsomega.3c05865"]}}