{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Lucke D"],"funding":["Deutsche Forschungsgemeinschaft","National Institute of General Medical Sciences","NIGMS NIH HHS","NIH HHS"],"pagination":["7349-7353"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10695670"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["25(40)"],"pubmed_abstract":["Herein, the synthesis of 1-hydroxy-2-naphthoic acid esters through an unexpected Lewis-acid-mediated 1,2-acyl shift of oxabenzonorbornadienes is reported. Using this methodology, novel substitution patterns for 1-hydroxy-2-naphtoic acid esters can be obtained. A mechanistic proposal and rationale for this transformation, the products of which had been previously incorrectly characterized, is given."],"journal":["Organic letters"],"pubmed_title":["Access to Naphthoic Acid Derivatives through an Oxabenzonorbornadiene Rearrangement."],"pmcid":["PMC10695670"],"funding_grant_id":["S10 OD024998","PE 3436/1","R35 GM130345","LU 2679/1-1"],"pubmed_authors":["Petzold M","Sarpong R","Campbell AS","Lucke D"],"additional_accession":[]},"is_claimable":false,"name":"Access to Naphthoic Acid Derivatives through an Oxabenzonorbornadiene Rearrangement.","description":"Herein, the synthesis of 1-hydroxy-2-naphthoic acid esters through an unexpected Lewis-acid-mediated 1,2-acyl shift of oxabenzonorbornadienes is reported. Using this methodology, novel substitution patterns for 1-hydroxy-2-naphtoic acid esters can be obtained. A mechanistic proposal and rationale for this transformation, the products of which had been previously incorrectly characterized, is given.","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Oct","modification":"2025-04-25T17:30:59.576Z","creation":"2025-04-06T05:37:58.565Z"},"accession":"S-EPMC10695670","cross_references":{"pubmed":["37795939"],"doi":["10.1021/acs.orglett.3c02823"]}}