{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["63(2)"],"submitter":["Shafikov MZ"],"pubmed_abstract":["Herein, we present two novel cyclometalated Ir(III) complexes of dinuclear and trinuclear design, <b>Ir</b><sub><b>2</b></sub><b>(dppm)</b><sub><b>3</b></sub><b>(acac)</b><sub><b>2</b></sub> and <b>Ir</b><sub><b>3</b></sub><b>(dppm)</b><sub><b>4</b></sub><b>(acac)</b><sub><b>3</b></sub>, respectively, where <b>dppm</b> is 4,6-di(4-tert-butylphenyl)pyrimidine ligand and <b>acac</b> is acetylacetonate ligand. In both cases, <i>rac</i>-diastereomers were isolated during the synthesis. The materials show intense phosphorescence of outstanding rates (<i>k</i><sub>r</sub> = Φ<sub>PL</sub>/τ) with corresponding radiative decay times of only τ<sub>r</sub> = 1/<i>k</i><sub>r</sub> = 0.36 μs for dinuclear <b>Ir</b><sub><b>2</b></sub><b>(dppm)</b><sub><b>3</b></sub><b>(acac)</b><sub><b>2</b></sub> an"],"journal":["Inorganic chemistry"],"pagination":["1317-1327"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10792602"],"repository":["biostudies-literature"],"pubmed_title":["Trinuclear Cyclometalated Iridium(III) Complex Exhibiting Intense Phosphorescence of an Unprecedented Rate."],"pmcid":["PMC10792602"],"pubmed_authors":["Zaytsev AV","Shafikov MZ","Kozhevnikov VN"],"additional_accession":[]},"is_claimable":false,"name":"Trinuclear Cyclometalated Iridium(III) Complex Exhibiting Intense Phosphorescence of an Unprecedented Rate.","description":"Herein, we present two novel cyclometalated Ir(III) complexes of dinuclear and trinuclear design, <b>Ir</b><sub><b>2</b></sub><b>(dppm)</b><sub><b>3</b></sub><b>(acac)</b><sub><b>2</b></sub> and <b>Ir</b><sub><b>3</b></sub><b>(dppm)</b><sub><b>4</b></sub><b>(acac)</b><sub><b>3</b></sub>, respectively, where <b>dppm</b> is 4,6-di(4-tert-butylphenyl)pyrimidine ligand and <b>acac</b> is acetylacetonate ligand. In both cases, <i>rac</i>-diastereomers were isolated during the synthesis. The materials show intense phosphorescence of outstanding rates (<i>k</i><sub>r</sub> = Φ<sub>PL</sub>/τ) with corresponding radiative decay times of only τ<sub>r</sub> = 1/<i>k</i><sub>r</sub> = 0.36 μs for dinuclear <b>Ir</b><sub><b>2</b></sub><b>(dppm)</b><sub><b>3</b></sub><b>(acac)</b><sub><b>2</b></sub> an","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Jan","modification":"2025-04-19T00:59:58.395Z","creation":"2025-04-07T11:58:52.489Z"},"accession":"S-EPMC10792602","cross_references":{"pubmed":["38154085"],"doi":["10.1021/acs.inorgchem.3c03810"]}}