{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Sinclair MJG"],"funding":["European Research Council","EUTOPIA alliance","Vrije Universiteit Brussel","Royal Society","Engineering and Physical Sciences Research Council"],"pagination":["1709-1713"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10828984"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["63(4)"],"pubmed_abstract":["The synthesis and characterization of a homologous series of T-shaped {MNO}<sup>10</sup> nitrosyl complexes of the form [M(PR<sub>3</sub>)<sub>2</sub>(NO)]<sup>+</sup> (M = Pd, Pt; R = <i>t</i>Bu, Ad) are reported. These diamagnetic nitrosyls are obtained from monovalent or zerovalent precursors by treatment with NO and NO<sup>+</sup>, respectively, and are notable for distinctly bent M-NO angles of ∼123° in the solid state. Adoption of this coordination mode in solution is also supported by the analysis of isotopically enriched samples by <sup>15</sup>N NMR spectroscopy. Effective oxidation states of M<sup>0</sup>/NO<sup>+</sup> are calculated, and metal-nitrosyl bonding has been interrogated using DFT-based energy decomposition analysis techniques. While a linear nitrosyl coordination mo"],"journal":["Inorganic chemistry"],"pubmed_title":["T-Shaped Palladium and Platinum {MNO}<sup>10</sup> Nitrosyl Complexes."],"pmcid":["PMC10828984"],"funding_grant_id":["co-tutelle studentship to N.R.","637313","DTP studentship to M.J.G.S.","UF150675","UF100592"],"pubmed_authors":["Tsoureas N","Gyton MR","Roig N","Chaplin AB","Alonso M","Sinclair MJG","Cloke FGN"],"additional_accession":[]},"is_claimable":false,"name":"T-Shaped Palladium and Platinum {MNO}<sup>10</sup> Nitrosyl Complexes.","description":"The synthesis and characterization of a homologous series of T-shaped {MNO}<sup>10</sup> nitrosyl complexes of the form [M(PR<sub>3</sub>)<sub>2</sub>(NO)]<sup>+</sup> (M = Pd, Pt; R = <i>t</i>Bu, Ad) are reported. These diamagnetic nitrosyls are obtained from monovalent or zerovalent precursors by treatment with NO and NO<sup>+</sup>, respectively, and are notable for distinctly bent M-NO angles of ∼123° in the solid state. Adoption of this coordination mode in solution is also supported by the analysis of isotopically enriched samples by <sup>15</sup>N NMR spectroscopy. Effective oxidation states of M<sup>0</sup>/NO<sup>+</sup> are calculated, and metal-nitrosyl bonding has been interrogated using DFT-based energy decomposition analysis techniques. While a linear nitrosyl coordination mo","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Jan","modification":"2025-04-26T10:28:37.51Z","creation":"2025-04-06T13:24:27.636Z"},"accession":"S-EPMC10828984","cross_references":{"pubmed":["38207212"],"doi":["10.1021/acs.inorgchem.3c03434"]}}