{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Xu H"],"funding":["Taishan Scholars Program, State Key Laboratory of Bio-Fibers and Eco-Textiles","Natural Science Foundation of Shandong Province","National Natural Science Foundation of China"],"pagination":["657"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10856751"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["29(3)"],"pubmed_abstract":["Transition metal phosphides (TMPs) have been widely studied for water decomposition for their monocatalytic property for anodic or cathodic reactions. However, their bifunctional catalytic activity still remains a major challenge. Herein, hexagonal nickel-cobalt bimetallic phosphide nanoneedles with 1-3 μm length and 15-30 nm diameter supported on NF (Ni<sub>x</sub>Co<sub>2-x</sub>P NDs/NF) with adjusted electron structure have been successfully prepared. The overall alkaline water electrolyzer composed of the optimal anode (Ni<sub>0.67</sub>Co<sub>1.33</sub>P NDs/NF) and cathode (Ni<sub>1.01</sub>Co<sub>0.99</sub>P NDs/NF) provide 100 mA cm<sup>-2</sup> at 1.62 V. Gibbs Free Energy for reaction paths proves that the active site in the hydrogen evolution reaction (HER) is Ni and the oxygen"],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["Electronic Structure Regulated Nickel-Cobalt Bimetal Phosphide Nanoneedles for Efficient Overall Water Splitting."],"pmcid":["PMC10856751"],"funding_grant_id":["ZR2021ME012 and ZR2021QB022","51672143, 22005165, 52102362, 51808303, 22075197, 22278290","Qingdao University No. ZFZ201809 and ZDKT202105"],"pubmed_authors":["Tan L","Li H","Diao L","Zou Y","Wang C","She X","Xu H","Chen S","Lu P","Li L","Sun J"],"additional_accession":[]},"is_claimable":false,"name":"Electronic Structure Regulated Nickel-Cobalt Bimetal Phosphide Nanoneedles for Efficient Overall Water Splitting.","description":"Transition metal phosphides (TMPs) have been widely studied for water decomposition for their monocatalytic property for anodic or cathodic reactions. However, their bifunctional catalytic activity still remains a major challenge. Herein, hexagonal nickel-cobalt bimetallic phosphide nanoneedles with 1-3 μm length and 15-30 nm diameter supported on NF (Ni<sub>x</sub>Co<sub>2-x</sub>P NDs/NF) with adjusted electron structure have been successfully prepared. The overall alkaline water electrolyzer composed of the optimal anode (Ni<sub>0.67</sub>Co<sub>1.33</sub>P NDs/NF) and cathode (Ni<sub>1.01</sub>Co<sub>0.99</sub>P NDs/NF) provide 100 mA cm<sup>-2</sup> at 1.62 V. Gibbs Free Energy for reaction paths proves that the active site in the hydrogen evolution reaction (HER) is Ni and the oxygen","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Jan","modification":"2025-04-05T14:51:21.876Z","creation":"2025-04-05T14:51:21.876Z"},"accession":"S-EPMC10856751","cross_references":{"pubmed":["38338401"],"doi":["10.3390/molecules29030657"]}}