biostudies-literatureHasan AMMUniversity Grants Commission of BangladeshMultidisciplinary University Research InitiativeMinistry of Science and Technology, Government of the People’s Republic of Bangladesh7616-7630https://www.ebi.ac.uk/biostudies/studies/S-EPMC10911412biostudies-literatureUnknown14(11)Dye-sensitized solar cells (DSSCs) play a crucial role in the realm of renewable energy technology by converting solar energy into electrical energy in an efficient and cost-effective way. In the pursuit of improving the photoconversion efficiency (PCE) of DSSCs, this work aims at fabricating a new counter electrode (CE) using a binary composite of heteroatom-doped carbon dots (C-dots) and functionalized multi-walled carbon nanotubes (o-MWCNTs). We demonstrate that this binary composite exhibits superior performance to pristine o-MWCNTs, resulting in a remarkable enhancement in the PCE. The PCE of the o-MWCNT/C-dots composite was measured at an impressive 4.28%, significantly outperforming the pristine o-MWCNT electrode, which yielded an efficiency of 2.24%. The enhanced performance of the o-MWCNT/C-dots composite can be attributed to the synergistic effects of heteroatom-doped C-dots since their binding to the o-MWCNTs by activated oxygenic surface functional groups increases the surface area from 218 to 253 m² g^-1. This enhanced surface area results from the reduction of π-π stacking interactions of the individual tubes and production of a new hollow channel in the structure that provides an ideal scaffold for I₂ adsorption and electron transfer. We demonstrate the role of C-dots on MWCNT's property modulation toward higher PCE by density functional theory (DFT) calculation and electrochemical analysis. Electron-excess N and S doped C-dots exhibit strong catalytic activity, allowing for rapid electron transfer processes in the CE-electrolyte surface <i>via</i> the donor acceptor mechanism, whereas electron-deficient B doped C-dots undermine the cell performance by forming a charge recombination trap at the CE surface. The synthesized composite has higher redox reversibility up to 100 CV cycles and chemical stability, studied by the post-performance material characterization. The findings offer a promising avenue for the development of high-performance DSSCs, which will help to promote sustainable and renewable energy technologies.RSC advancesSynergism in carbon nanotubes and carbon-dots: counter electrode of a high-performance dye-sensitized solar cell.PMC10911412W911NF2310260Hasan AMMSusan MABHfalseSynergism in carbon nanotubes and carbon-dots: counter electrode of a high-performance dye-sensitized solar cell.Dye-sensitized solar cells (DSSCs) play a crucial role in the realm of renewable energy technology by converting solar energy into electrical energy in an efficient and cost-effective way. In the pursuit of improving the photoconversion efficiency (PCE) of DSSCs, this work aims at fabricating a new counter electrode (CE) using a binary composite of heteroatom-doped carbon dots (C-dots) and functionalized multi-walled carbon nanotubes (o-MWCNTs). We demonstrate that this binary composite exhibits superior performance to pristine o-MWCNTs, resulting in a remarkable enhancement in the PCE. The PCE of the o-MWCNT/C-dots composite was measured at an impressive 4.28%, significantly outperforming the pristine o-MWCNT electrode, which yielded an efficiency of 2.24%. The enhanced performance of the o-MWCNT/C-dots composite can be attributed to the synergistic effects of heteroatom-doped C-dots since their binding to the o-MWCNTs by activated oxygenic surface functional groups increases the surface area from 218 to 253 m² g^-1. This enhanced surface area results from the reduction of π-π stacking interactions of the individual tubes and production of a new hollow channel in the structure that provides an ideal scaffold for I₂ adsorption and electron transfer. We demonstrate the role of C-dots on MWCNT's property modulation toward higher PCE by density functional theory (DFT) calculation and electrochemical analysis. Electron-excess N and S doped C-dots exhibit strong catalytic activity, allowing for rapid electron transfer processes in the CE-electrolyte surface <i>via</i> the donor acceptor mechanism, whereas electron-deficient B doped C-dots undermine the cell performance by forming a charge recombination trap at the CE surface. The synthesized composite has higher redox reversibility up to 100 CV cycles and chemical stability, studied by the post-performance material characterization. The findings offer a promising avenue for the development of high-performance DSSCs, which will help to promote sustainable and renewable energy technologies.2024-01-01T00:00:00Z2024 Feb2026-06-16T04:50:04.759Z2025-04-06T17:15:06.608ZS-EPMC109114123844028410.1039/d4ra00601a