biostudies-literatureSghyar RTulane UniversityHacettepe University Scientific Research Project Unit262-266https://www.ebi.ac.uk/biostudies/studies/S-EPMC10915674biostudies-literatureUnknown80(Pt 3)The title mol-ecule, [Fe₂(C₅H₅)₂(C₂₃H₁₇ClN₂)]·C₃H₇NO, is twisted end to end and the central N/C/N unit is disordered. In the crystal, several C-H⋯π(ring) inter-actions lead to the formation of layers, which are connected by further C-H⋯π(ring) inter-actions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H⋯H (60.2%) and H⋯C/C⋯H (27.0%) inter-actions. Hydrogen bonding, C-H⋯π(ring) inter-actions and van der Waals inter-actions dominate the crystal packing.Acta crystallographica. Section E, Crystallographic communicationsCrystal structure and Hirshfeld surface analysis of (<i>Z</i>)-<i>N</i>-{chloro-[(4-ferrocenylphen-yl)imino]-meth-yl}-4-ferrocenylaniline <i>N</i>,<i>N</i>-di-methyl-formamide monosolvate.PMC10915674013 D04 602 004Hokelek TSebbar NKMazzah ABentama ASghyar REl Hadrami EMMague JTHaoudi AfalseCrystal structure and Hirshfeld surface analysis of (<i>Z</i>)-<i>N</i>-{chloro-[(4-ferrocenylphen-yl)imino]-meth-yl}-4-ferrocenylaniline <i>N</i>,<i>N</i>-di-methyl-formamide monosolvate.The title mol-ecule, [Fe₂(C₅H₅)₂(C₂₃H₁₇ClN₂)]·C₃H₇NO, is twisted end to end and the central N/C/N unit is disordered. In the crystal, several C-H⋯π(ring) inter-actions lead to the formation of layers, which are connected by further C-H⋯π(ring) inter-actions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H⋯H (60.2%) and H⋯C/C⋯H (27.0%) inter-actions. Hydrogen bonding, C-H⋯π(ring) inter-actions and van der Waals inter-actions dominate the crystal packing.2024-01-01T00:00:00Z2024 Mar2026-06-15T03:17:58.848Z2026-06-15T03:09:01.963ZS-EPMC109156743845604610.1107/S2056989024001002