{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ye R"],"funding":["Natural Science Foundation of Jiangxi Province","Natural Science Foundation of Jiangxi Province (Jiangxi Province Natural Science Foundation)","National Natural Science Foundation of China","National Natural Science Foundation of China (National Science Foundation of China)"],"pagination":["2159"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10924954"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["15(1)"],"pubmed_abstract":["CO<sub>2</sub> hydrogenation to chemicals and fuels is a significant approach for achieving carbon neutrality. It is essential to rationally design the chemical structure and catalytic active sites towards the development of efficient catalysts. Here we show a Ce-CuZn catalyst with enriched Cu/Zn-O<sub>V</sub>-Ce active sites fabricated through the atomic-level substitution of Cu and Zn into Ce-MOF precursor. The Ce-CuZn catalyst exhibits a high methanol selectivity of 71.1% and a space-time yield of methanol up to 400.3 g·kg<sub>cat</sub><sup>-1</sup>·h<sup>-1</sup> with excellent stability for 170 h at 260 °C, comparable to that of the state-of-the-art CuZnAl catalysts. Controlled experiments and DFT calculations confirm that the incorporation of Cu and Zn into CeO<sub>2</sub> with abund"],"journal":["Nature communications"],"pubmed_title":["A Ce-CuZn catalyst with abundant Cu/Zn-O<sub>V</sub>-Ce active sites for CO<sub>2</sub> hydrogenation to methanol."],"pmcid":["PMC10924954"],"funding_grant_id":["22005296","U23A20132","20232ACB213001;20224BAB213015"],"pubmed_authors":["Liu J","Duyar MS","Ma L","Wang B","Ma Y","Zhang R","Mao J","Jiang Z","Gallo A","Hong X","Ye R","Luo W","Wang X"],"additional_accession":[]},"is_claimable":false,"name":"A Ce-CuZn catalyst with abundant Cu/Zn-O<sub>V</sub>-Ce active sites for CO<sub>2</sub> hydrogenation to methanol.","description":"CO<sub>2</sub> hydrogenation to chemicals and fuels is a significant approach for achieving carbon neutrality. It is essential to rationally design the chemical structure and catalytic active sites towards the development of efficient catalysts. Here we show a Ce-CuZn catalyst with enriched Cu/Zn-O<sub>V</sub>-Ce active sites fabricated through the atomic-level substitution of Cu and Zn into Ce-MOF precursor. The Ce-CuZn catalyst exhibits a high methanol selectivity of 71.1% and a space-time yield of methanol up to 400.3 g·kg<sub>cat</sub><sup>-1</sup>·h<sup>-1</sup> with excellent stability for 170 h at 260 °C, comparable to that of the state-of-the-art CuZnAl catalysts. Controlled experiments and DFT calculations confirm that the incorporation of Cu and Zn into CeO<sub>2</sub> with abund","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Mar","modification":"2025-04-04T12:58:32.243Z","creation":"2025-04-04T12:58:32.243Z"},"accession":"S-EPMC10924954","cross_references":{"pubmed":["38461315"],"doi":["10.1038/s41467-024-46513-3"]}}