{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Liu J"],"funding":["Natural Science Foundation of Jiangxi Province","Natural Science Foundation of Jiangxi Province (Jiangxi Province Natural Science Foundation)","National Natural Science Foundation of China","National Natural Science Foundation of China (National Science Foundation of China)"],"pagination":["2222"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10933363"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["15(1)"],"pubmed_abstract":["Iso-butene (iso-C<sub>4</sub>H<sub>8</sub>) is an important raw material in chemical industry, whereas its efficient separation remains challenging due to similar molecular properties of C<sub>4</sub> olefins. The ideal adsorbent should possess simultaneous high uptakes for 1,3-butadiene (C<sub>4</sub>H<sub>6</sub>) and n-butene (n-C<sub>4</sub>H<sub>8</sub>) counterparts, endowing high efficiency for iso-C<sub>4</sub>H<sub>8</sub> separation in adsorption columns. Herein, a sulfate-pillared adsorbent, SOFOUR-DPDS-Ni (DPDS = 4,4'-dipyridyldisulfide), is reported for the efficient iso-C<sub>4</sub>H<sub>8</sub> separation from binary and ternary C<sub>4</sub> olefin mixtures. The rigidity in pore sizes and shapes of SOFOUR-DPDS-Ni exerts the molecular sieving of iso-C<sub>4</sub>H<sub>8</su"],"journal":["Nature communications"],"pubmed_title":["Molecular sieving of iso-butene from C<sub>4</sub> olefins with simultaneous high 1,3-butadiene and n-butene uptakes."],"pmcid":["PMC10933363"],"funding_grant_id":["20224ACB204003","22268029","22168023","22322807"],"pubmed_authors":["Peng Y","Deng S","Liu J","Chen J","Zeng Z","Shuai H","Zhao Z","Wang J","Wang L","Zhou Z","Liu X","Wang P","Deng Z","Chen S","Xiong H"],"additional_accession":[]},"is_claimable":false,"name":"Molecular sieving of iso-butene from C<sub>4</sub> olefins with simultaneous high 1,3-butadiene and n-butene uptakes.","description":"Iso-butene (iso-C<sub>4</sub>H<sub>8</sub>) is an important raw material in chemical industry, whereas its efficient separation remains challenging due to similar molecular properties of C<sub>4</sub> olefins. The ideal adsorbent should possess simultaneous high uptakes for 1,3-butadiene (C<sub>4</sub>H<sub>6</sub>) and n-butene (n-C<sub>4</sub>H<sub>8</sub>) counterparts, endowing high efficiency for iso-C<sub>4</sub>H<sub>8</sub> separation in adsorption columns. Herein, a sulfate-pillared adsorbent, SOFOUR-DPDS-Ni (DPDS = 4,4'-dipyridyldisulfide), is reported for the efficient iso-C<sub>4</sub>H<sub>8</sub> separation from binary and ternary C<sub>4</sub> olefin mixtures. The rigidity in pore sizes and shapes of SOFOUR-DPDS-Ni exerts the molecular sieving of iso-C<sub>4</sub>H<sub>8</su","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Mar","modification":"2026-07-14T22:09:36.95Z","creation":"2024-12-04T10:53:05.717Z"},"accession":"S-EPMC10933363","cross_references":{"pubmed":["38472257"],"doi":["10.1038/s41467-024-46607-y"]}}