{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Gao X"],"funding":["Engineering and Physical Sciences Research Council"],"pagination":["e202300608"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10946563"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["62(16)"],"pubmed_abstract":["The electrochemical effect of isotope (EEI) of water is introduced in the Zn-ion batteries (ZIBs) electrolyte to deal with the challenge of severe side reactions and massive gas production. Due to the low diffusion and strong coordination of ions in D<sub>2</sub> O, the possibility of side reactions is decreased, resulting in a broader electrochemically stable potential window, less pH change, and less zinc hydroxide sulfate (ZHS) generation during cycling. Moreover, we demonstrate that D<sub>2</sub> O eliminates the different ZHS phases generated by the change of bound water during cycling because of the consistently low local ion and molecule concentration, resulting in a stable interface between the electrode and electrolyte. The full cells with D<sub>2</sub> O-based electrolyte demonst"],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["When It's Heavier: Interfacial and Solvation Chemistry of Isotopes in Aqueous Electrolytes for Zn-ion Batteries."],"pmcid":["PMC10946563"],"funding_grant_id":["EP/V027433/1","EP/V027433/3","EP/V027433/2","EP/V027433/1; EP/V027433/2"],"pubmed_authors":["Li J","Zong W","He G","Hu X","He H","Du Z","Dai Y","Zhang W","Wang M","Liu Y","Parkin IP","Zhu J","Zhao S","Dong H","Zhang Y","Carmalt CJ","Guo F","Zhao F","Gao X","Zhang C","Chen R"],"additional_accession":[]},"is_claimable":false,"name":"When It's Heavier: Interfacial and Solvation Chemistry of Isotopes in Aqueous Electrolytes for Zn-ion Batteries.","description":"The electrochemical effect of isotope (EEI) of water is introduced in the Zn-ion batteries (ZIBs) electrolyte to deal with the challenge of severe side reactions and massive gas production. Due to the low diffusion and strong coordination of ions in D<sub>2</sub> O, the possibility of side reactions is decreased, resulting in a broader electrochemically stable potential window, less pH change, and less zinc hydroxide sulfate (ZHS) generation during cycling. Moreover, we demonstrate that D<sub>2</sub> O eliminates the different ZHS phases generated by the change of bound water during cycling because of the consistently low local ion and molecule concentration, resulting in a stable interface between the electrode and electrolyte. The full cells with D<sub>2</sub> O-based electrolyte demonst","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Apr","modification":"2025-04-20T02:50:06.167Z","creation":"2025-02-19T03:09:24.803Z"},"accession":"S-EPMC10946563","cross_references":{"pubmed":["36809576"],"doi":["10.1002/anie.202300608"]}}