{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Franz R"],"funding":["János Bolyai Research Scholarship and Project","German Science Fund"],"pagination":["e2306805"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10953586"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["11(11)"],"pubmed_abstract":["Coordination of a stereochemically defined P<sub>3</sub> -chain to a series of transition metal carbonyls [M(CO)<sub>x</sub> ]<sup>z-</sup> (M = Mn (x = 5, z = 1), Fe (x = 4, z = 2) or Co (x = 4, z = 1)) is explored using a [3]ferrocenophane scaffold. A gradual transition from η<sup>1</sup> -, η<sup>2</sup> - to η<sup>3</sup> -coordination is observed where in the η<sup>2</sup> -mode the terminal positions of the phosphorus chain are bridged. With an excess of cobalt carbonyl successive P-P bond activation and gradual separation of the central phosphorus atoms from the phosphorus chain has been observed. This process is reversible and with suitable reagents such as methyl lithium, the P<sub>3</sub> -unit is regenerated in stereospecific manner. The bonding situation and steps of the gradua"],"journal":["Advanced science (Weinheim, Baden-Wurttemberg, Germany)"],"pubmed_title":["Gradual Coordination and Reversible P-P Bond Activation of a P<sub>3</sub> -Unit with Transition Metal Carbonyls."],"pmcid":["PMC10953586"],"funding_grant_id":["UNKP-22-5-BME-298","CRC 1319"],"pubmed_authors":["Gal D","Kelemen Z","Franz R","Pietschnig R","Bruhn C"],"additional_accession":[]},"is_claimable":false,"name":"Gradual Coordination and Reversible P-P Bond Activation of a P<sub>3</sub> -Unit with Transition Metal Carbonyls.","description":"Coordination of a stereochemically defined P<sub>3</sub> -chain to a series of transition metal carbonyls [M(CO)<sub>x</sub> ]<sup>z-</sup> (M = Mn (x = 5, z = 1), Fe (x = 4, z = 2) or Co (x = 4, z = 1)) is explored using a [3]ferrocenophane scaffold. A gradual transition from η<sup>1</sup> -, η<sup>2</sup> - to η<sup>3</sup> -coordination is observed where in the η<sup>2</sup> -mode the terminal positions of the phosphorus chain are bridged. With an excess of cobalt carbonyl successive P-P bond activation and gradual separation of the central phosphorus atoms from the phosphorus chain has been observed. This process is reversible and with suitable reagents such as methyl lithium, the P<sub>3</sub> -unit is regenerated in stereospecific manner. The bonding situation and steps of the gradua","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Mar","modification":"2026-06-01T18:55:17.335Z","creation":"2024-11-20T19:05:37.016Z"},"accession":"S-EPMC10953586","cross_references":{"pubmed":["38161225"],"doi":["10.1002/advs.202306805"]}}