{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Stanitska M"],"funding":["Simons Foundation","Ministry of Education and Science of Ukraine","Lietuvos Mokslo Taryba"],"pagination":["14613-14626"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10976381"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(12)"],"pubmed_abstract":["The synthesis of four 4-(carbazolyl-<i>R</i>-benzoyl)-5-CF<sub>3</sub>-1<i>H</i>-1,2,3-triazoles with extra groups ((3-methyl)-phenyl-, 4-fluorophenyl-, quinolinyl-, or (3-trifluoromethyl)-phenyl-) in the acceptor fragment has been reported. The effects of substituents with different electron-withdrawing strengths on the thermal, electrochemical, photophysical, and electroluminescence properties of the synthesized compounds are discussed. The results of X-ray analyses and density functional theory (DFT) calculations support unusual molecular packing and electronic properties. The compounds are capable of glass formation with glass transition temperatures ranging from 54-84 °C. Ionization potentials of the compounds are in the range of 5.98-6.22 eV and electron affinities range from 3.09 to"],"journal":["ACS omega"],"pubmed_title":["Effects of Electron-Withdrawing Strengths of the Substituents on the Properties of 4-(Carbazolyl-<i>R</i>-benzoyl)-5-CF<sub>3</sub>-1<i>H</i>-1,2,3-triazole Derivatives as Blue Emitters for Doping-Free Electroluminescence Devices."],"pmcid":["PMC10976381"],"funding_grant_id":["1037973","S-MIP-22-78"],"pubmed_authors":["Grazulevicius JV","Pokhodylo N","Obushak M","Lytvyn R","Kutsiy S","Keruckiene R","Kinzhybalo V","Volyniuk D","Stakhira P","Urbonas E","Stanitska M","Ivaniuk K"],"additional_accession":[]},"is_claimable":false,"name":"Effects of Electron-Withdrawing Strengths of the Substituents on the Properties of 4-(Carbazolyl-<i>R</i>-benzoyl)-5-CF<sub>3</sub>-1<i>H</i>-1,2,3-triazole Derivatives as Blue Emitters for Doping-Free Electroluminescence Devices.","description":"The synthesis of four 4-(carbazolyl-<i>R</i>-benzoyl)-5-CF<sub>3</sub>-1<i>H</i>-1,2,3-triazoles with extra groups ((3-methyl)-phenyl-, 4-fluorophenyl-, quinolinyl-, or (3-trifluoromethyl)-phenyl-) in the acceptor fragment has been reported. The effects of substituents with different electron-withdrawing strengths on the thermal, electrochemical, photophysical, and electroluminescence properties of the synthesized compounds are discussed. The results of X-ray analyses and density functional theory (DFT) calculations support unusual molecular packing and electronic properties. The compounds are capable of glass formation with glass transition temperatures ranging from 54-84 °C. Ionization potentials of the compounds are in the range of 5.98-6.22 eV and electron affinities range from 3.09 to","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Mar","modification":"2025-04-22T08:22:38.039Z","creation":"2025-04-22T08:22:38.039Z"},"accession":"S-EPMC10976381","cross_references":{"pubmed":["38559965"],"doi":["10.1021/acsomega.4c01077"]}}