{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Keshari K"],"funding":["Indian Institute of Technology Delhi","Ministerio de Ciencia, Innovaci?n y Universidades","Science and Engineering Research Board","Consejo Superior de Investigaciones Cient?ficas","Council of Scientific and Industrial Research, India"],"pagination":["1142-1154"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC10976569"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["4(3)"],"pubmed_abstract":["Herein, we show that the reaction of a mononuclear Fe<sup>III</sup>(OH) complex (<b>1</b>) with <i>N</i>-tosyliminobenzyliodinane (PhINTs) resulted in the formation of a Fe<sup>IV</sup>(OH) species (<b>3</b>). The obtained complex <b>3</b> was characterized by an array of spectroscopic techniques and represented a rare example of a synthetic Fe<sup>IV</sup>(OH) complex. The reaction of <b>1</b> with the one-electron oxidizing agent was reported to form a ligand-oxidized Fe<sup>III</sup>(OH) complex (<b>2</b>). <b>3</b> revealed a one-electron reduction potential of -0.22 V vs Fc<sup>+</sup>/Fc at -15 °C, which was 150 mV anodically shifted than <b>2</b> (<i>E</i><sub>red</sub> = -0.37 V vs Fc<sup>+</sup>/Fc at -15 °C), inferring <b>3</b> to be more oxidizing than <b>2</b>. <b>3</b> reacted"],"journal":["JACS Au"],"pubmed_title":["Functional Model of Compound II of Cytochrome P450: Spectroscopic Characterization and Reactivity Studies of a Fe<sup>IV</sup>-OH Complex."],"pmcid":["PMC10976569"],"funding_grant_id":["RYC2020-029863-I","01(2981)/19/EMR-II","CNS2023-145046","TED2021-132757B-I00","CRG/2022/005842","PID2019-111086RA-I00","PID2022-143013OB-I00","20226AT001"],"pubmed_authors":["Keshari K","Ugale AD","Marco JF","Moonshiram D","Sauvan M","Velasco L","Paria S","Santra A","Kaur S","Munshi S"],"additional_accession":[]},"is_claimable":false,"name":"Functional Model of Compound II of Cytochrome P450: Spectroscopic Characterization and Reactivity Studies of a Fe<sup>IV</sup>-OH Complex.","description":"Herein, we show that the reaction of a mononuclear Fe<sup>III</sup>(OH) complex (<b>1</b>) with <i>N</i>-tosyliminobenzyliodinane (PhINTs) resulted in the formation of a Fe<sup>IV</sup>(OH) species (<b>3</b>). The obtained complex <b>3</b> was characterized by an array of spectroscopic techniques and represented a rare example of a synthetic Fe<sup>IV</sup>(OH) complex. The reaction of <b>1</b> with the one-electron oxidizing agent was reported to form a ligand-oxidized Fe<sup>III</sup>(OH) complex (<b>2</b>). <b>3</b> revealed a one-electron reduction potential of -0.22 V vs Fc<sup>+</sup>/Fc at -15 °C, which was 150 mV anodically shifted than <b>2</b> (<i>E</i><sub>red</sub> = -0.37 V vs Fc<sup>+</sup>/Fc at -15 °C), inferring <b>3</b> to be more oxidizing than <b>2</b>. <b>3</b> reacted","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Mar","modification":"2025-04-22T08:16:10.292Z","creation":"2025-04-05T22:32:17.979Z"},"accession":"S-EPMC10976569","cross_references":{"pubmed":["38559734"],"doi":["10.1021/jacsau.3c00844"]}}