{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Kelsey SR"],"funding":["National Science Foundation Graduate Research Fellowship Program","NCRR NIH HHS","NIH Office of the Director","National Science Foundation"],"pagination":["5213-5216"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11080966"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["60(39)"],"pubmed_abstract":["The <i>E</i><sub>1/2</sub> potential associated with reduction of the linearly-functionalized 6,6'-biazulenic scaffold is accurately correlated to the combined <i>σ</i><sub>p</sub> Hammett parameters of the substituents over >600 mV range. X-ray crystallographic analysis of the 2,2'-dichloro-substituted derivative revealed unexpectedly short C-Cl bond distances, along with other metric changes, suggesting a non-trivial cycloheptafulvalene-like structural contribution."],"journal":["Chemical communications (Cambridge, England)"],"pubmed_title":["Tuning the redox profile of the 6,6'-biazulenic platform through functionalization along its molecular axis."],"pmcid":["PMC11080966"],"funding_grant_id":["P20 GM103418","MRI-2117449","S10 RR024664","CHE-9977422","DGE-1940699","CHE-1808120","MRI-1125975","CHE-1625923","S10OD016360","S10RR024664"],"pubmed_authors":["Kelsey SR","Barybin MV","Griaznov G","Spaeth AD","Douglas JT","Janzen DE","Thompson WH"],"additional_accession":[]},"is_claimable":false,"name":"Tuning the redox profile of the 6,6'-biazulenic platform through functionalization along its molecular axis.","description":"The <i>E</i><sub>1/2</sub> potential associated with reduction of the linearly-functionalized 6,6'-biazulenic scaffold is accurately correlated to the combined <i>σ</i><sub>p</sub> Hammett parameters of the substituents over >600 mV range. X-ray crystallographic analysis of the 2,2'-dichloro-substituted derivative revealed unexpectedly short C-Cl bond distances, along with other metric changes, suggesting a non-trivial cycloheptafulvalene-like structural contribution.","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 May","modification":"2026-05-29T09:37:11.427Z","creation":"2026-05-19T03:07:15.453Z"},"accession":"S-EPMC11080966","cross_references":{"pubmed":["38652073"],"doi":["10.1039/d4cc00656a"]}}