{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ichimaru Y"],"funding":["Kinjo Gakuin University-Parent Teacher Association Research Grants","Japan Society for the Promotion of Science (JSPS) JSPS KAKENHI Grants"],"pagination":["x240665"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11299653"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(Pt 7)"],"pubmed_abstract":["In the title salt, [ZnCl(C<sub>23</sub>H<sub>30</sub>N<sub>4</sub>)]NO<sub>3</sub>, the central Zn<sup>II</sup> atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitro-gen atoms from cyclen (1,4,7,10-tetra-aza-cyclo-dodeca-ne) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through inter-molecular T-shaped π inter-actions. Additionally, the nitrate anion participates in inter-molecular N-H⋯O hydrogen bonds with cyclen."],"journal":["IUCrData"],"pubmed_title":["[1-(Anthracen-9-ylmeth-yl)-1,4,7,10-tetra-aza-cyclododeca-ne]chlorido-zinc(II) nitrate."],"pmcid":["PMC11299653"],"funding_grant_id":["JP21K06500","JP23K14339"],"pubmed_authors":["Kurosaki H","Jin W","Kato K","Kondo Y","Sugiura K","Kurihara M","Ichimaru Y","Imai M"],"additional_accession":[]},"is_claimable":false,"name":"[1-(Anthracen-9-ylmeth-yl)-1,4,7,10-tetra-aza-cyclododeca-ne]chlorido-zinc(II) nitrate.","description":"In the title salt, [ZnCl(C<sub>23</sub>H<sub>30</sub>N<sub>4</sub>)]NO<sub>3</sub>, the central Zn<sup>II</sup> atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitro-gen atoms from cyclen (1,4,7,10-tetra-aza-cyclo-dodeca-ne) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through inter-molecular T-shaped π inter-actions. Additionally, the nitrate anion participates in inter-molecular N-H⋯O hydrogen bonds with cyclen.","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Jul","modification":"2025-04-26T05:29:43.008Z","creation":"2025-04-06T11:30:26.747Z"},"accession":"S-EPMC11299653","cross_references":{"pubmed":["39108938"],"doi":["10.1107/S2414314624006655"]}}