biostudies-literatureIchimaru YKinjo Gakuin University-Parent Teacher Association Research GrantsJapan Society for the Promotion of Science (JSPS) JSPS KAKENHI Grantsx240665https://www.ebi.ac.uk/biostudies/studies/S-EPMC11299653biostudies-literatureUnknown9(Pt 7)In the title salt, [ZnCl(C₂₃H₃₀N₄)]NO₃, the central Zn^II atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitro-gen atoms from cyclen (1,4,7,10-tetra-aza-cyclo-dodeca-ne) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through inter-molecular T-shaped π inter-actions. Additionally, the nitrate anion participates in inter-molecular N-H⋯O hydrogen bonds with cyclen.IUCrData[1-(Anthracen-9-ylmeth-yl)-1,4,7,10-tetra-aza-cyclododeca-ne]chlorido-zinc(II) nitrate.PMC11299653JP21K06500JP23K14339Kurosaki HJin WKato KKondo YSugiura KKurihara MIchimaru YImai Mfalse[1-(Anthracen-9-ylmeth-yl)-1,4,7,10-tetra-aza-cyclododeca-ne]chlorido-zinc(II) nitrate.In the title salt, [ZnCl(C₂₃H₃₀N₄)]NO₃, the central Zn^II atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitro-gen atoms from cyclen (1,4,7,10-tetra-aza-cyclo-dodeca-ne) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through inter-molecular T-shaped π inter-actions. Additionally, the nitrate anion participates in inter-molecular N-H⋯O hydrogen bonds with cyclen.2024-01-01T00:00:00Z2024 Jul2025-04-26T05:29:43.008Z2025-04-06T11:30:26.747ZS-EPMC112996533910893810.1107/S2414314624006655