{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["9(Pt 7)"],"submitter":["Yaffa L"],"pubmed_abstract":["The title compound, (C<sub>2</sub>H<sub>10</sub>N<sub>2</sub>)<sub>2</sub>[(C<sub>10</sub>H<sub>12</sub>N<sub>2</sub>O<sub>8</sub>)(MoO<sub>3</sub>)<sub>2</sub>]·4H<sub>2</sub>O, which crystallizes in the monoclinic <i>C</i>2/<i>c</i> space group, was obtained by mixing molybdenum oxide, ethyl-enedi-amine and ethyl-enedi-amine-tetra-acetic acid (H<sub>4</sub>edta) in a 2:4:1 ratio. The complex anion contains two MoO<sub>3</sub> units bridged by an edta<sup>4-</sup> anion. The midpoint of the central C-C bond of the edta<sup>4-</sup> anion is located on a crystallographic inversion centre. The independent Mo atom is tridentately coordin-ated by a nitro-gen atom and two carboxyl-ate groups of the edta<sup>4-</sup> ligand, together with the three oxo ligands, producing a distorted octa-hedral coordination environment. In the three-dimensional supra-molecular crystal structure, the dinuclear anions, the organo-ammonium counter-ions and the solvent water mol-ecules are linked by N-H⋯O<sub>w</sub>, N-H⋯O<sub>edta</sub> and O-H⋯O hydrogen bonds."],"journal":["IUCrData"],"pagination":["x240667"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11299656"],"repository":["biostudies-literature"],"pubmed_title":["Bis(ethyl-enedi-ammonium) μ-ethyl-enedi-aminetetra-acetato-1κ<sup>3</sup> <i>O</i>,<i>N</i>,<i>O</i>':2κ<sup>3</sup> <i>O</i>'',<i>N</i>',<i>O</i>'''-bis-[tri-oxidomolybdate(VI)] tetra-hydrate."],"pmcid":["PMC11299656"],"pubmed_authors":["Kama AB","Diop CAK","Toure A","Yaffa L","Seye D"],"additional_accession":[]},"is_claimable":false,"name":"Bis(ethyl-enedi-ammonium) μ-ethyl-enedi-aminetetra-acetato-1κ<sup>3</sup> <i>O</i>,<i>N</i>,<i>O</i>':2κ<sup>3</sup> <i>O</i>'',<i>N</i>',<i>O</i>'''-bis-[tri-oxidomolybdate(VI)] tetra-hydrate.","description":"The title compound, (C<sub>2</sub>H<sub>10</sub>N<sub>2</sub>)<sub>2</sub>[(C<sub>10</sub>H<sub>12</sub>N<sub>2</sub>O<sub>8</sub>)(MoO<sub>3</sub>)<sub>2</sub>]·4H<sub>2</sub>O, which crystallizes in the monoclinic <i>C</i>2/<i>c</i> space group, was obtained by mixing molybdenum oxide, ethyl-enedi-amine and ethyl-enedi-amine-tetra-acetic acid (H<sub>4</sub>edta) in a 2:4:1 ratio. The complex anion contains two MoO<sub>3</sub> units bridged by an edta<sup>4-</sup> anion. The midpoint of the central C-C bond of the edta<sup>4-</sup> anion is located on a crystallographic inversion centre. The independent Mo atom is tridentately coordin-ated by a nitro-gen atom and two carboxyl-ate groups of the edta<sup>4-</sup> ligand, together with the three oxo ligands, producing a distorted octa-hedral coordination environment. In the three-dimensional supra-molecular crystal structure, the dinuclear anions, the organo-ammonium counter-ions and the solvent water mol-ecules are linked by N-H⋯O<sub>w</sub>, N-H⋯O<sub>edta</sub> and O-H⋯O hydrogen bonds.","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Jul","modification":"2024-11-15T07:17:14.028Z","creation":"2024-11-15T07:17:14.028Z"},"accession":"S-EPMC11299656","cross_references":{"pubmed":["39108940"],"doi":["10.1107/S2414314624006679"]}}