{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Anzaldo B"],"funding":["Consejo Nacional de Ciencia y Tecnología"],"pagination":["x240555"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11299657"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(Pt 7)"],"pubmed_abstract":["The Pd<sup>II</sup> complex bis-{(<i>S</i>)-(-)-<i>N</i>-[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κ<i>N</i>}di-chlorido-palladium(II), [PdCl<sub>2</sub>(C<sub>22</sub>H<sub>21</sub>NO)<sub>2</sub>], crystallizes in the monoclinic Sohncke space group <i>P</i>2<sub>1</sub> with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N-Pd-Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd-Cl and Pd-N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features inter-molecular N-H⋯Cl and intramolecular C-H⋯Pd inter-actions, which lead to the formation of a supramolecular framework structure."],"journal":["IUCrData"],"pubmed_title":["Bis{(<i>S</i>)-(-)-<i>N</i>-[(2-biphen-yl)methyl-idene]-1-(4-meth-oxy-phen-yl)ethyl-amine-κ<i>N</i>}di-chlorido-palladium(II)."],"pmcid":["PMC11299657"],"funding_grant_id":["368610"],"pubmed_authors":["Moreno Morales GE","Anzaldo B","Gutierrez Perez R","Hernandez Tellez G","Mendoza A"],"additional_accession":[]},"is_claimable":false,"name":"Bis{(<i>S</i>)-(-)-<i>N</i>-[(2-biphen-yl)methyl-idene]-1-(4-meth-oxy-phen-yl)ethyl-amine-κ<i>N</i>}di-chlorido-palladium(II).","description":"The Pd<sup>II</sup> complex bis-{(<i>S</i>)-(-)-<i>N</i>-[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κ<i>N</i>}di-chlorido-palladium(II), [PdCl<sub>2</sub>(C<sub>22</sub>H<sub>21</sub>NO)<sub>2</sub>], crystallizes in the monoclinic Sohncke space group <i>P</i>2<sub>1</sub> with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N-Pd-Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd-Cl and Pd-N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features inter-molecular N-H⋯Cl and intramolecular C-H⋯Pd inter-actions, which lead to the formation of a supramolecular framework structure.","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Jul","modification":"2025-04-05T11:07:31.548Z","creation":"2024-11-12T05:44:28.912Z"},"accession":"S-EPMC11299657","cross_references":{"pubmed":["39108936"],"doi":["10.1107/S2414314624005558"]}}