biostudies-literatureAnzaldo BConsejo Nacional de Ciencia y Tecnologíax240555https://www.ebi.ac.uk/biostudies/studies/S-EPMC11299657biostudies-literatureUnknown9(Pt 7)The Pd^II complex bis-{(<i>S</i>)-(-)-<i>N</i>-[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κ<i>N</i>}di-chlorido-palladium(II), [PdCl₂(C₂₂H₂₁NO)₂], crystallizes in the monoclinic Sohncke space group <i>P</i>2₁ with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N-Pd-Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd-Cl and Pd-N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features inter-molecular N-H⋯Cl and intramolecular C-H⋯Pd inter-actions, which lead to the formation of a supramolecular framework structure.IUCrDataBis{(<i>S</i>)-(-)-<i>N</i>-[(2-biphen-yl)methyl-idene]-1-(4-meth-oxy-phen-yl)ethyl-amine-κ<i>N</i>}di-chlorido-palladium(II).PMC11299657368610Moreno Morales GEAnzaldo BGutierrez Perez RHernandez Tellez GMendoza AfalseBis{(<i>S</i>)-(-)-<i>N</i>-[(2-biphen-yl)methyl-idene]-1-(4-meth-oxy-phen-yl)ethyl-amine-κ<i>N</i>}di-chlorido-palladium(II).The Pd^II complex bis-{(<i>S</i>)-(-)-<i>N</i>-[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κ<i>N</i>}di-chlorido-palladium(II), [PdCl₂(C₂₂H₂₁NO)₂], crystallizes in the monoclinic Sohncke space group <i>P</i>2₁ with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N-Pd-Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd-Cl and Pd-N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features inter-molecular N-H⋯Cl and intramolecular C-H⋯Pd inter-actions, which lead to the formation of a supramolecular framework structure.2024-01-01T00:00:00Z2024 Jul2025-04-05T11:07:31.548Z2024-11-12T05:44:28.912ZS-EPMC112996573910893610.1107/S2414314624005558