<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><submitter>Yang XG</submitter><funding>National Natural Science Foundation of China</funding><pubmed_abstract>Phosphor-converted white light-emitting diodes (PC-WLEDs) have attracted considerable attention in solid-state lighting and display. However, urgent issues of thermal quenching and high cost remain formidable challenges. Herein, a novel metal-organic framework (MOF) phosphor [CdCl&lt;sub>2&lt;/sub>(AD)] was facilely prepared using a mixture of CdCl&lt;sub>2&lt;/sub> and acridine (AD) under solvothermal conditions. It shows intensive green emission with a long lifetime of 31.88 ns and quantum yield of 65% while maintaining 95% and 84% of its initial emission intensity after remaining immersed in water for 60 days and being heated to 150 °C, respectively. The low thermal quenching of this MOF material is comparable to or can even exceed that of commercial inorganic phosphors. The combination of experime</pubmed_abstract><journal>Chemical science</journal><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC11322981</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Low thermal quenching of metal halide-based metal-organic framework phosphor for light-emitting diodes.</pubmed_title><pmcid>PMC11322981</pmcid><funding_grant_id>21971100</funding_grant_id><funding_grant_id>22371109</funding_grant_id><funding_grant_id>22171123</funding_grant_id><pubmed_authors>Yang XG</pubmed_authors><pubmed_authors>Li Y</pubmed_authors><pubmed_authors>Chen YJ</pubmed_authors><pubmed_authors>Li YM</pubmed_authors><pubmed_authors>Yin PP</pubmed_authors><pubmed_authors>Yang SY</pubmed_authors><pubmed_authors>Ma LF</pubmed_authors></additional><is_claimable>false</is_claimable><name>Low thermal quenching of metal halide-based metal-organic framework phosphor for light-emitting diodes.</name><description>Phosphor-converted white light-emitting diodes (PC-WLEDs) have attracted considerable attention in solid-state lighting and display. However, urgent issues of thermal quenching and high cost remain formidable challenges. Herein, a novel metal-organic framework (MOF) phosphor [CdCl&lt;sub>2&lt;/sub>(AD)] was facilely prepared using a mixture of CdCl&lt;sub>2&lt;/sub> and acridine (AD) under solvothermal conditions. It shows intensive green emission with a long lifetime of 31.88 ns and quantum yield of 65% while maintaining 95% and 84% of its initial emission intensity after remaining immersed in water for 60 days and being heated to 150 °C, respectively. The low thermal quenching of this MOF material is comparable to or can even exceed that of commercial inorganic phosphors. The combination of experime</description><dates><release>2024-01-01T00:00:00Z</release><publication>2024 Jul</publication><modification>2026-06-01T16:24:22.253Z</modification><creation>2025-04-06T19:29:50.071Z</creation></dates><accession>S-EPMC11322981</accession><cross_references><pubmed>39149214</pubmed><doi>10.1039/d4sc04228j</doi></cross_references></HashMap>