{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"submitter":["Xia RQ"],"funding":["Guangzhou Municipal Science and Technology Project","National Natural Science Foundation of China"],"pubmed_abstract":["The development of metal complexes for photosynthesis of hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) from pure water and oxygen using solar energy, especially in the absence of any additives (<i>e.g.</i>, acid, co-catalysts, and sacrificial agents), is a worthwhile pursuit, yet still remains highly challenging. More importantly, the O<sub>2</sub> evolution from the water oxidation reaction has been impeded by the classic bottleneck, the photon-flux-density problem of sunlight that could be attributed to rarefied solar radiation for a long time. Herein, we reported synthesis of boron dipyrromethene (BODIPY)-based cyclic trinuclear silver complexes (Ag-CTC), and they exhibited strong visible-light absorption ability, a suitable energy bandgap, excellent photochemical properties and effici"],"journal":["Chemical science"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11333952"],"repository":["biostudies-literature"],"pubmed_title":["A cyclic trinuclear silver complex for photosynthesis of hydrogen peroxide."],"pmcid":["PMC11333952"],"funding_grant_id":["21731002","202201020038","22150004","22371091","21975104","92261205"],"pubmed_authors":["Xia RQ","Liu ZN","Tang YY","Li D","Wei RJ","Luo X","Wu T","Ning GH"],"additional_accession":[]},"is_claimable":false,"name":"A cyclic trinuclear silver complex for photosynthesis of hydrogen peroxide.","description":"The development of metal complexes for photosynthesis of hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) from pure water and oxygen using solar energy, especially in the absence of any additives (<i>e.g.</i>, acid, co-catalysts, and sacrificial agents), is a worthwhile pursuit, yet still remains highly challenging. More importantly, the O<sub>2</sub> evolution from the water oxidation reaction has been impeded by the classic bottleneck, the photon-flux-density problem of sunlight that could be attributed to rarefied solar radiation for a long time. Herein, we reported synthesis of boron dipyrromethene (BODIPY)-based cyclic trinuclear silver complexes (Ag-CTC), and they exhibited strong visible-light absorption ability, a suitable energy bandgap, excellent photochemical properties and effici","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Aug","modification":"2026-06-03T00:40:36.219Z","creation":"2025-04-04T02:57:31.99Z"},"accession":"S-EPMC11333952","cross_references":{"pubmed":["39170716"],"doi":["10.1039/d4sc04098h"]}}