{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["16(1)"],"submitter":["Jiang X"],"pubmed_abstract":["Electrocatalytic 5-hydroxymethylfurfural oxidation reaction (HMFOR) provides a promising strategy to convert biomass derivative to high-value-added chemicals. Herein, a cascade strategy is proposed to construct Pd-NiCo<sub>2</sub>O<sub>4</sub> electrocatalyst by Pd loading on Ni-doped Co<sub>3</sub>O<sub>4</sub> and for highly active and stable synergistic HMF oxidation. An elevated current density of 800 mA cm<sup>-2</sup> can be achieved at 1.5 V, and both Faradaic efficiency and yield of 2,5-furandicarboxylic acid remained close to 100% over 10 consecutive electrolysis. Experimental and theoretical results unveil that the introduction of Pd atoms can modulate the local electronic structure of Ni/Co, which not only balances the competitive adsorption of HMF and OH<sup>-</sup> species, bu"],"journal":["Nano-micro letters"],"pagination":["275"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11339012"],"repository":["biostudies-literature"],"pubmed_title":["Enhancing the Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Through Cascade Structure Tuning for Highly Stable Biomass Upgrading."],"pmcid":["PMC11339012"],"pubmed_authors":["Liu Y","Yang Y","Zhao L","Wang P","Zhang Y","Jiang X","Ma X","Lin Y","Wei Y"],"additional_accession":[]},"is_claimable":false,"name":"Enhancing the Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Through Cascade Structure Tuning for Highly Stable Biomass Upgrading.","description":"Electrocatalytic 5-hydroxymethylfurfural oxidation reaction (HMFOR) provides a promising strategy to convert biomass derivative to high-value-added chemicals. Herein, a cascade strategy is proposed to construct Pd-NiCo<sub>2</sub>O<sub>4</sub> electrocatalyst by Pd loading on Ni-doped Co<sub>3</sub>O<sub>4</sub> and for highly active and stable synergistic HMF oxidation. An elevated current density of 800 mA cm<sup>-2</sup> can be achieved at 1.5 V, and both Faradaic efficiency and yield of 2,5-furandicarboxylic acid remained close to 100% over 10 consecutive electrolysis. Experimental and theoretical results unveil that the introduction of Pd atoms can modulate the local electronic structure of Ni/Co, which not only balances the competitive adsorption of HMF and OH<sup>-</sup> species, bu","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Aug","modification":"2025-04-04T02:19:41.247Z","creation":"2025-04-04T02:19:41.247Z"},"accession":"S-EPMC11339012","cross_references":{"pubmed":["39168930"],"doi":["10.1007/s40820-024-01493-3"]}}