{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["11(10)"],"submitter":["Shi J"],"pubmed_abstract":["Using the electrochemical polyol oxidation reaction (POR) to produce formic acid over nickel-based oxides/hydroxides (NiO <i><sub>x</sub></i> H <i><sub>y</sub></i> ) is an attractive strategy for the electrochemical upgrading of biomass-derived polyols. The key step in the POR, i.e. the cleavage of the C-C bond, depends on an oxygen-vacancy-induced mechanism. However, a high-energy oxygen vacancy is usually ineffective for Schottky-type oxygen-vacancy-rich β-Ni(OH)<sub>2</sub> (V<sub>SO</sub>-β-Ni(OH)<sub>2</sub>). As a result, both β-Ni(OH)<sub>2</sub> and V<sub>SO</sub>-β-Ni(OH)<sub>2</sub> cannot continuously catalyze oxygen-vacancy-induced C-C bond cleavage during PORs. Here, we report a strategy of oxygen-vacancy-filling with sulfur to synthesize a β-Ni(OH)<sub>2</sub> (S-V<sub>O</sub"],"journal":["National science review"],"pagination":["nwae271"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11409883"],"repository":["biostudies-literature"],"pubmed_title":["Sulfur filling activates vacancy-induced C-C bond cleavage in polyol electrooxidation."],"pmcid":["PMC11409883"],"pubmed_authors":["Jiang Y","Zou Y","Zhu Y","Chen W","Dong CL","Shi J","Huang YC","Wu Y","Xie C"],"additional_accession":[]},"is_claimable":false,"name":"Sulfur filling activates vacancy-induced C-C bond cleavage in polyol electrooxidation.","description":"Using the electrochemical polyol oxidation reaction (POR) to produce formic acid over nickel-based oxides/hydroxides (NiO <i><sub>x</sub></i> H <i><sub>y</sub></i> ) is an attractive strategy for the electrochemical upgrading of biomass-derived polyols. The key step in the POR, i.e. the cleavage of the C-C bond, depends on an oxygen-vacancy-induced mechanism. However, a high-energy oxygen vacancy is usually ineffective for Schottky-type oxygen-vacancy-rich β-Ni(OH)<sub>2</sub> (V<sub>SO</sub>-β-Ni(OH)<sub>2</sub>). As a result, both β-Ni(OH)<sub>2</sub> and V<sub>SO</sub>-β-Ni(OH)<sub>2</sub> cannot continuously catalyze oxygen-vacancy-induced C-C bond cleavage during PORs. Here, we report a strategy of oxygen-vacancy-filling with sulfur to synthesize a β-Ni(OH)<sub>2</sub> (S-V<sub>O</sub","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Oct","modification":"2025-04-04T01:14:45.562Z","creation":"2025-04-04T01:14:45.562Z"},"accession":"S-EPMC11409883","cross_references":{"pubmed":["39301081"],"doi":["10.1093/nsr/nwae271"]}}