{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["36(19)"],"submitter":["Marin I"],"pubmed_abstract":["Herein, we report the first examples of supramolecular systems from bent-core-based pillar[<i>n</i>]arenes through ionic bonds. These ionic materials have been prepared by the interaction of an amino-ended pillar[5]arene (P5N10) and three different carboxylic acids, including bent-core moieties. The bent-core units are based on ester, biphenyl, and azobenzene structures bearing two different flexible spacers between the carboxyl group and the central bent-core aromatic units. The ionic pairs segregate the molecular blocks, leading to columnar liquid crystal organizations. These ionic supramolecular compounds exhibit interesting results as proton-conductive materials. Furthermore, the introduction of azobenzene units in the bent-core structure has provided a photoresponse to the proton cond"],"journal":["Chemistry of materials : a publication of the American Chemical Society"],"pagination":["9793-9805"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11468781"],"repository":["biostudies-literature"],"pubmed_title":["Ionic Bent-Core Pillar[&lt;i&gt;n&lt;/i&gt;]arenes: From Liquid Crystals to Nanoaggregates and Functional Applications."],"pmcid":["PMC11468781"],"pubmed_authors":["Serrano JL","Marin I","Ros MB","Barbera J","Merino RI","Folcia CL","Castillo-Valles M"],"additional_accession":[]},"is_claimable":false,"name":"Ionic Bent-Core Pillar[&lt;i&gt;n&lt;/i&gt;]arenes: From Liquid Crystals to Nanoaggregates and Functional Applications.","description":"Herein, we report the first examples of supramolecular systems from bent-core-based pillar[<i>n</i>]arenes through ionic bonds. These ionic materials have been prepared by the interaction of an amino-ended pillar[5]arene (P5N10) and three different carboxylic acids, including bent-core moieties. The bent-core units are based on ester, biphenyl, and azobenzene structures bearing two different flexible spacers between the carboxyl group and the central bent-core aromatic units. The ionic pairs segregate the molecular blocks, leading to columnar liquid crystal organizations. These ionic supramolecular compounds exhibit interesting results as proton-conductive materials. Furthermore, the introduction of azobenzene units in the bent-core structure has provided a photoresponse to the proton cond","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Oct","modification":"2025-04-04T07:41:14.524Z","creation":"2025-04-04T07:41:14.524Z"},"accession":"S-EPMC11468781","cross_references":{"pubmed":["39398374"],"doi":["10.1021/acs.chemmater.4c01952"]}}