{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Chin WK"],"funding":["U.S. Department of Energy","National Science Foundation"],"pagination":["4574"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11477724"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["29(19)"],"pubmed_abstract":["The spin crossover complex Fe(phen)<sub>2</sub>(NCS)<sub>2</sub> and its composite, Fe(phen)<sub>2</sub>(NCS)<sub>2</sub>, combined with the conducting polymer polyaniline (PANI) plus varying concentrations of iron magnetite (Fe<sub>3</sub>O<sub>4</sub>) nanoparticles were studied. A cooperative effect is evident from the hysteresis width in the plot of magnetic susceptibility multiplied by temperature versus temperature (χmT versus T) for Fe(phen)<sub>2</sub>(NCS)<sub>2</sub> with PANI plus varying concentrations of Fe<sub>3</sub>O<sub>4</sub> nanoparticles. The hysteresis width in the composites vary no more than 2 K with respect to the pristine Fe(phen)<sub>2</sub>(NCS)<sub>2</sub> spin crossover crystallites despite the fact that there exists a high degree of miscibility of the Fe(phen"],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["Evidence of Cooperative Effects for the Fe(phen)&lt;sub&gt;2&lt;/sub&gt;(NCS)&lt;sub&gt;2&lt;/sub&gt; Spin Crossover Molecular Complex in Polyaniline Plus Iron Magnetite."],"pmcid":["PMC11477724"],"funding_grant_id":["2317464","2044049","DE-AC02-05CH11231","1827690"],"pubmed_authors":["Viswan G","Dowben PA","Lai RY","Tamang B","Subedi A","Chin WK","Zaz MZ","N'Diaye AT"],"additional_accession":[]},"is_claimable":false,"name":"Evidence of Cooperative Effects for the Fe(phen)&lt;sub&gt;2&lt;/sub&gt;(NCS)&lt;sub&gt;2&lt;/sub&gt; Spin Crossover Molecular Complex in Polyaniline Plus Iron Magnetite.","description":"The spin crossover complex Fe(phen)<sub>2</sub>(NCS)<sub>2</sub> and its composite, Fe(phen)<sub>2</sub>(NCS)<sub>2</sub>, combined with the conducting polymer polyaniline (PANI) plus varying concentrations of iron magnetite (Fe<sub>3</sub>O<sub>4</sub>) nanoparticles were studied. A cooperative effect is evident from the hysteresis width in the plot of magnetic susceptibility multiplied by temperature versus temperature (χmT versus T) for Fe(phen)<sub>2</sub>(NCS)<sub>2</sub> with PANI plus varying concentrations of Fe<sub>3</sub>O<sub>4</sub> nanoparticles. The hysteresis width in the composites vary no more than 2 K with respect to the pristine Fe(phen)<sub>2</sub>(NCS)<sub>2</sub> spin crossover crystallites despite the fact that there exists a high degree of miscibility of the Fe(phen","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Sep","modification":"2025-04-04T13:54:38.043Z","creation":"2025-04-04T13:54:38.043Z"},"accession":"S-EPMC11477724","cross_references":{"pubmed":["39407504"],"doi":["10.3390/molecules29194574"]}}